TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)

TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)

2+2 Cyclocondensation of 1,5-diaminopentane with beta-diketones viz. 2,3-pentanedione, 2,3- hexanedione or 1-phenyl -1,2- propanedione in the presence of alkaline earth metal ions as templates yield a series of hexacoordinated complexes of the type [ML(X2)] ( where L=N4 macrocyle having 18-membered...

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Autores principales: PRASAD,R N., GUPTA,SEEMA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2004
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100005
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spelling oai:scielo:S0717-970720040001000052004-05-11TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)PRASAD,R N.GUPTA,SEEMA2+2 Cyclocondensation of 1,5-diaminopentane with beta-diketones viz. 2,3-pentanedione, 2,3- hexanedione or 1-phenyl -1,2- propanedione in the presence of alkaline earth metal ions as templates yield a series of hexacoordinated complexes of the type [ML(X2)] ( where L=N4 macrocyle having 18-membered ring and X = Cl or NCS) The resulting complexes have been characterized by elemental analyses, conductance measurements, IR and ¹H NMR spectrainfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.1 20042004-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100005en10.4067/S0717-97072004000100005
institution Scielo Chile
collection Scielo Chile
language English
description 2+2 Cyclocondensation of 1,5-diaminopentane with beta-diketones viz. 2,3-pentanedione, 2,3- hexanedione or 1-phenyl -1,2- propanedione in the presence of alkaline earth metal ions as templates yield a series of hexacoordinated complexes of the type [ML(X2)] ( where L=N4 macrocyle having 18-membered ring and X = Cl or NCS) The resulting complexes have been characterized by elemental analyses, conductance measurements, IR and ¹H NMR spectra
author PRASAD,R N.
GUPTA,SEEMA
spellingShingle PRASAD,R N.
GUPTA,SEEMA
TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
author_facet PRASAD,R N.
GUPTA,SEEMA
author_sort PRASAD,R N.
title TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
title_short TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
title_full TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
title_fullStr TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
title_full_unstemmed TEMPLATE SYNTHESIS OF 2,11-DIMETHYL-3,12-DIETHYL / PROPYL / PHENYL-1,4,10,13-TETRAAZACYCLOOCTADECA-1,3,10,12-TETRAENE COMPLEXES OF Mg(II), Ca(II), Sr(II) AND Ba(II)
title_sort template synthesis of 2,11-dimethyl-3,12-diethyl / propyl / phenyl-1,4,10,13-tetraazacyclooctadeca-1,3,10,12-tetraene complexes of mg(ii), ca(ii), sr(ii) and ba(ii)
publisher Sociedad Chilena de Química
publishDate 2004
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100005
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AT guptaseema templatesynthesisof211dimethyl312diethylpropylphenyl141013tetraazacyclooctadeca131012tetraenecomplexesofmgiicaiisriiandbaii
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