CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES

A potentiometric all-solid-state type ion-selective electrode (ISE) for NO3- was constructed and characterized. It is based on a mixture of tetra-decyl-ammonium nitrate (TDAN) as ionophore, di-butyl phthalate (DBP) as plasticizer and poly (vinyl chloride) (PVC) as matrix. Nitrate concentrations in t...

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Autores principales: ARADA PÉREZ,MARÍA DE LOS A., CORTES NODARSE,ISEL, YAZDANI-PEDRAM,MEHRDAD
Lenguaje:English
Publicado: Sociedad Chilena de Química 2004
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100006
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spelling oai:scielo:S0717-970720040001000062004-05-11CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOESARADA PÉREZ,MARÍA DE LOS A.CORTES NODARSE,ISELYAZDANI-PEDRAM,MEHRDAD ion-selective electrode (ISE) nitrate, tetra-decyl-ammonium nitrate liquid membranes plasticizer poly(vinyl chloride) A potentiometric all-solid-state type ion-selective electrode (ISE) for NO3- was constructed and characterized. It is based on a mixture of tetra-decyl-ammonium nitrate (TDAN) as ionophore, di-butyl phthalate (DBP) as plasticizer and poly (vinyl chloride) (PVC) as matrix. Nitrate concentrations in tomatoes samples, randomly collected from central market at Santiago de Cuba, were determined using the described ISE by standard addition potentiometry. Spectrophotometric determinations using Brucine were performed as comparative method. Accurate and precise results were obtained. Accordingly, an analytical procedure for NO3- determination in tomatoes using the constructed ISE could be formulatedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.1 20042004-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100006en10.4067/S0717-97072004000100006
institution Scielo Chile
collection Scielo Chile
language English
topic ion-selective electrode (ISE)
nitrate, tetra-decyl-ammonium nitrate
liquid membranes
plasticizer
poly(vinyl chloride)
spellingShingle ion-selective electrode (ISE)
nitrate, tetra-decyl-ammonium nitrate
liquid membranes
plasticizer
poly(vinyl chloride)
ARADA PÉREZ,MARÍA DE LOS A.
CORTES NODARSE,ISEL
YAZDANI-PEDRAM,MEHRDAD
CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
description A potentiometric all-solid-state type ion-selective electrode (ISE) for NO3- was constructed and characterized. It is based on a mixture of tetra-decyl-ammonium nitrate (TDAN) as ionophore, di-butyl phthalate (DBP) as plasticizer and poly (vinyl chloride) (PVC) as matrix. Nitrate concentrations in tomatoes samples, randomly collected from central market at Santiago de Cuba, were determined using the described ISE by standard addition potentiometry. Spectrophotometric determinations using Brucine were performed as comparative method. Accurate and precise results were obtained. Accordingly, an analytical procedure for NO3- determination in tomatoes using the constructed ISE could be formulated
author ARADA PÉREZ,MARÍA DE LOS A.
CORTES NODARSE,ISEL
YAZDANI-PEDRAM,MEHRDAD
author_facet ARADA PÉREZ,MARÍA DE LOS A.
CORTES NODARSE,ISEL
YAZDANI-PEDRAM,MEHRDAD
author_sort ARADA PÉREZ,MARÍA DE LOS A.
title CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
title_short CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
title_full CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
title_fullStr CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
title_full_unstemmed CONSTRUCTION OF A POLYMERIC LIQUID-MEMBRANE ION-SELECTIVE ELECTRODE (ISE)AND ITS APPLICATION FOR DETERMINATION OF NITRATE IN TOMATOES
title_sort construction of a polymeric liquid-membrane ion-selective electrode (ise)and its application for determination of nitrate in tomatoes
publisher Sociedad Chilena de Química
publishDate 2004
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100006
work_keys_str_mv AT aradaperezmariadelosa constructionofapolymericliquidmembraneionselectiveelectrodeiseanditsapplicationfordeterminationofnitrateintomatoes
AT cortesnodarseisel constructionofapolymericliquidmembraneionselectiveelectrodeiseanditsapplicationfordeterminationofnitrateintomatoes
AT yazdanipedrammehrdad constructionofapolymericliquidmembraneionselectiveelectrodeiseanditsapplicationfordeterminationofnitrateintomatoes
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