A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolat...
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| Auteurs principaux: | , , , |
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| Langue: | English |
| Publié: |
Sociedad Chilena de Química
2004
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| Accès en ligne: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300002 |
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| Résumé: | The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussed |
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