A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+

The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolat...

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Autores principales:	Díaz,C, Spodine,E, Moreno,Y, Carrasco,E
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2004
Materias:	cyclophosphazenes iron-thiolates magnetic properties sulphur ligands
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300002
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spelling	oai:scielo:S0717-970720040003000022006-03-21A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+Díaz,CSpodine,EMoreno,YCarrasco,E cyclophosphazenes iron-thiolates magnetic properties sulphur ligands The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.3 20042004-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300002en10.4067/S0717-97072004000300002
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	cyclophosphazenes iron-thiolates magnetic properties sulphur ligands
spellingShingle	cyclophosphazenes iron-thiolates magnetic properties sulphur ligands Díaz,C Spodine,E Moreno,Y Carrasco,E A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
description	The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussed
author	Díaz,C Spodine,E Moreno,Y Carrasco,E
author_facet	Díaz,C Spodine,E Moreno,Y Carrasco,E
author_sort	Díaz,C
title	A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
title_short	A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
title_full	A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
title_fullStr	A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
title_full_unstemmed	A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
title_sort	one step functionalization, coordination of n3p3cl6 using [cpfe(dppe)sc6h4oh]+
publisher	Sociedad Chilena de Química
publishDate	2004
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300002
work_keys_str_mv	AT diazc aonestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT spodinee aonestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT morenoy aonestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT carrascoe aonestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT diazc onestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT spodinee onestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT morenoy onestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh AT carrascoe onestepfunctionalizationcoordinationofn3p3cl6usingcpfedppesc6h4oh
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A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+

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