POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION

Polymeric liquid membranes are prepared using (3-nitro-o-xylene (NOX), tri-butylphosphate (TBP), bis-(2-ethylhexyl) sebacate (DOS), o-nitrophenyloctyl ether (o-NPOE), tris-2-ethylhexylphosphate (TEHP), dioctylphthalate (DOP) and dibutylphthalate (DBP) as plasticizers, and they have been used as sens...

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Autores principales:	ARADA PÉREZ,MARÍA DE LOS ANGELES, YAZDANI-PEDRAM,MEHRDAD
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2004
Materias:	ion-selective electrode nitrate ion tri-octylmethyl ammonium chloride liquid membranes poly(vinyl chloride)
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300007
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spelling	oai:scielo:S0717-970720040003000072006-03-21POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATIONARADA PÉREZ,MARÍA DE LOS ANGELESYAZDANI-PEDRAM,MEHRDAD ion-selective electrode nitrate ion tri-octylmethyl ammonium chloride liquid membranes poly(vinyl chloride) Polymeric liquid membranes are prepared using (3-nitro-o-xylene (NOX), tri-butylphosphate (TBP), bis-(2-ethylhexyl) sebacate (DOS), o-nitrophenyloctyl ether (o-NPOE), tris-2-ethylhexylphosphate (TEHP), dioctylphthalate (DOP) and dibutylphthalate (DBP) as plasticizers, and they have been used as sensors for nitrate ion, employing tri-octylmethyl ammonium chloride (TOMACl) as ionosphere and poly(vinyl chloride) (PVC) as matrix. The sensors showed Nernstian slopes with values of the practical detection limit (PDL) and lower limit of linear response (LLLR) in the concentration range of 10-6 10-5mol/dm³. All the electrodes built showed a fast and stable response of 15 seconds. Wide working pH ranges, especially in the alkaline region, were observed. The response of the sensors was determined in relation to the lipophilicity of each plasticizer used as solvent-mediator, its dielectric constant (e r), polarity and viscosityinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.3 20042004-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300007en10.4067/S0717-97072004000300007
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	ion-selective electrode nitrate ion tri-octylmethyl ammonium chloride liquid membranes poly(vinyl chloride)
spellingShingle	ion-selective electrode nitrate ion tri-octylmethyl ammonium chloride liquid membranes poly(vinyl chloride) ARADA PÉREZ,MARÍA DE LOS ANGELES YAZDANI-PEDRAM,MEHRDAD POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
description	Polymeric liquid membranes are prepared using (3-nitro-o-xylene (NOX), tri-butylphosphate (TBP), bis-(2-ethylhexyl) sebacate (DOS), o-nitrophenyloctyl ether (o-NPOE), tris-2-ethylhexylphosphate (TEHP), dioctylphthalate (DOP) and dibutylphthalate (DBP) as plasticizers, and they have been used as sensors for nitrate ion, employing tri-octylmethyl ammonium chloride (TOMACl) as ionosphere and poly(vinyl chloride) (PVC) as matrix. The sensors showed Nernstian slopes with values of the practical detection limit (PDL) and lower limit of linear response (LLLR) in the concentration range of 10-6 10-5mol/dm³. All the electrodes built showed a fast and stable response of 15 seconds. Wide working pH ranges, especially in the alkaline region, were observed. The response of the sensors was determined in relation to the lipophilicity of each plasticizer used as solvent-mediator, its dielectric constant (e r), polarity and viscosity
author	ARADA PÉREZ,MARÍA DE LOS ANGELES YAZDANI-PEDRAM,MEHRDAD
author_facet	ARADA PÉREZ,MARÍA DE LOS ANGELES YAZDANI-PEDRAM,MEHRDAD
author_sort	ARADA PÉREZ,MARÍA DE LOS ANGELES
title	POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
title_short	POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
title_full	POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
title_fullStr	POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
title_full_unstemmed	POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION
title_sort	potentiometric response of polymeric liquid membranes based on quaternary ammonium salts for nitrate ion determination
publisher	Sociedad Chilena de Química
publishDate	2004
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300007
work_keys_str_mv	AT aradaperezmariadelosangeles potentiometricresponseofpolymericliquidmembranesbasedonquaternaryammoniumsaltsfornitrateiondetermination AT yazdanipedrammehrdad potentiometricresponseofpolymericliquidmembranesbasedonquaternaryammoniumsaltsfornitrateiondetermination
_version_	1718445340609216512

POTENTIOMETRIC RESPONSE OF POLYMERIC LIQUID MEMBRANES BASED ON QUATERNARY AMMONIUM SALTS FOR NITRATE ION DETERMINATION

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