LOWER RIM p-TERT-BUTYLCALIX[4]ARENE DERIVATIVES CONTAINING GALACTITOL PENDANTS: COMPLEXATION OF 5,11,17,23-TETRAKIS-(1,1-DIMETHYLETHYL)-25,27-DIHYDROXY -26,28-BIS-2-N-(1-DEOXY-D-GALACTITYL)-AMINOETHOXYCALIX[4]ARENE WITH Pb(II) AND F(-I)

LOWER RIM p-TERT-BUTYLCALIX[4]ARENE DERIVATIVES CONTAINING GALACTITOL PENDANTS: COMPLEXATION OF 5,11,17,23-TETRAKIS-(1,1-DIMETHYLETHYL)-25,27-DIHYDROXY -26,28-BIS-2-N-(1-DEOXY-D-GALACTITYL)-AMINOETHOXYCALIX[4]ARENE WITH Pb(II) AND F(-I)

Reductive amination of D-galactose with the bisubstituted p-tert-butylcalix[4]arylethylamine in the presence of sodium cyanoborohydride allowed the introduction of one or two galactitol residues as pendants on the lower rim. The bisubstituted secondary amine, 5,11,17,23-tetrakis-(1,1-dimethylethyl)-...

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Bibliographic Details
Main Authors: CACERES,PABLO J, COSTAMAGNA,JUAN, DE NAMOR,ANGELA DANIL, MATSUHIRO,BETTY
Language:English
Published: Sociedad Chilena de Química 2004
Subjects:
calix-sugars
galactitol derivatives of calix[4]arenes
ligands
complexation
Online Access:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400002
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