VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS

The complex species formed in aqueous solution (25 °C, I = 3.0 mol.dm-3 KCl ionic medium) between V3+ cation and the dicarboxylic acids oxalic, malonic and succinic (H2L) have been studied potentiometrically. The application of the least-squares computer program LETAGROP to the experimental (emf H)...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	BRIUCAL,JULIO, LUBES,VITO, ARAUJO,MARY LORENA, BRITO,FELIPE
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2004
Materias:	Vanadium(III) complexes Solution equilibria Potentiometric studies Stability constants Speciation
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400003
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072004000400003
record_format	dspace
spelling	oai:scielo:S0717-970720040004000032005-09-13VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDSBRIUCAL,JULIOLUBES,VITOARAUJO,MARY LORENABRITO,FELIPE Vanadium(III) complexes Solution equilibria Potentiometric studies Stability constants Speciation The complex species formed in aqueous solution (25 °C, I = 3.0 mol.dm-3 KCl ionic medium) between V3+ cation and the dicarboxylic acids oxalic, malonic and succinic (H2L) have been studied potentiometrically. The application of the least-squares computer program LETAGROP to the experimental (emf H) data, taking into account the hydrolytic species of V3+ ion, indicates that under the experimental conditions employed the complexes [VHL]2+, [VL]+, [V(OH)L], [V(OH)2L]-, [VL2]-, [V(OH)L2]2-, [VL3]3- and [V(OH)L3]4- with oxalic acid, the complexes [VHL]2+, [VL]+, [VL2]-, [V(OH)L2]2-, [V(OH)2L2]3-, [VL3]3- and [V(OH)L3]4- with malonic acid, and the [VL]+ and [V(OH)L] complexes with succinic acid were formed. The stability constants of the complexes formed were determinedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.4 20042004-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400003en10.4067/S0717-97072004000400003
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Vanadium(III) complexes Solution equilibria Potentiometric studies Stability constants Speciation
spellingShingle	Vanadium(III) complexes Solution equilibria Potentiometric studies Stability constants Speciation BRIUCAL,JULIO LUBES,VITO ARAUJO,MARY LORENA BRITO,FELIPE VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
description	The complex species formed in aqueous solution (25 °C, I = 3.0 mol.dm-3 KCl ionic medium) between V3+ cation and the dicarboxylic acids oxalic, malonic and succinic (H2L) have been studied potentiometrically. The application of the least-squares computer program LETAGROP to the experimental (emf H) data, taking into account the hydrolytic species of V3+ ion, indicates that under the experimental conditions employed the complexes [VHL]2+, [VL]+, [V(OH)L], [V(OH)2L]-, [VL2]-, [V(OH)L2]2-, [VL3]3- and [V(OH)L3]4- with oxalic acid, the complexes [VHL]2+, [VL]+, [VL2]-, [V(OH)L2]2-, [V(OH)2L2]3-, [VL3]3- and [V(OH)L3]4- with malonic acid, and the [VL]+ and [V(OH)L] complexes with succinic acid were formed. The stability constants of the complexes formed were determined
author	BRIUCAL,JULIO LUBES,VITO ARAUJO,MARY LORENA BRITO,FELIPE
author_facet	BRIUCAL,JULIO LUBES,VITO ARAUJO,MARY LORENA BRITO,FELIPE
author_sort	BRIUCAL,JULIO
title	VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
title_short	VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
title_full	VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
title_fullStr	VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
title_full_unstemmed	VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS
title_sort	vanadium(iii) complexes in aqueous solution with the dicarboxylic oxalic, malonic and succinic acids
publisher	Sociedad Chilena de Química
publishDate	2004
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400003
work_keys_str_mv	AT briucaljulio vanadiumiiicomplexesinaqueoussolutionwiththedicarboxylicoxalicmalonicandsuccinicacids AT lubesvito vanadiumiiicomplexesinaqueoussolutionwiththedicarboxylicoxalicmalonicandsuccinicacids AT araujomarylorena vanadiumiiicomplexesinaqueoussolutionwiththedicarboxylicoxalicmalonicandsuccinicacids AT britofelipe vanadiumiiicomplexesinaqueoussolutionwiththedicarboxylicoxalicmalonicandsuccinicacids
_version_	1718445342589976576

VANADIUM(III) COMPLEXES IN AQUEOUS SOLUTION WITH THE DICARBOXYLIC OXALIC, MALONIC AND SUCCINIC ACIDS

Ejemplares similares