PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2

PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2

The crystal structure of the compound with empirical formula [Cu (2, 2'-BP)Cl NO3]2 (BP: 2,2'-bipyridine) (1) has been determined. Crystals are triclinic, space group P-1 with a = 7.5152(12) Å, b = 9.2531(14) Å, c = 10.2834(16) Å, alpha =112.181(2)º, beta = 102.155(2)º, gamma = 105.617(2)º...

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Autores principales: ATRIA,A.M., CORTÉS,P, ACEVEDO,L, TRUJILLO,R, MANZUR,J, PEÑA,O, BAGGIO,R
Lenguaje:English
Publicado: Sociedad Chilena de Química 2004
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400013
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spelling oai:scielo:S0717-970720040004000132005-09-13PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2ATRIA,A.M.CORTÉS,PACEVEDO,LTRUJILLO,RMANZUR,JPEÑA,OBAGGIO,RThe crystal structure of the compound with empirical formula [Cu (2, 2'-BP)Cl NO3]2 (BP: 2,2'-bipyridine) (1) has been determined. Crystals are triclinic, space group P-1 with a = 7.5152(12) Å, b = 9.2531(14) Å, c = 10.2834(16) Å, alpha =112.181(2)º, beta = 102.155(2)º, gamma = 105.617(2)º. The copper atom displays a (4+1) square pyramidal coordination, with the four in-plane bonds provided by one chloride ion, two nitrogen atoms from the 2,2'-bipyridine molecule and one oxygen from the nitrate group. The apical position corresponds to a chloride ion Cl(1') from a centrosymmetric neighboring moiety. The two symmetry related Cl ions bridge two copper atoms, generating a dimeric unit (Cu(1)-Cl(1) = 2.2726(11) Å, Cu(1)-Cl (1') = 2.7093(13) Å). Magnetic susceptibility measurements showed a weak ferromagnetic interaction between dimersinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.49 n.4 20042004-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400013en10.4067/S0717-97072004000400013
institution Scielo Chile
collection Scielo Chile
language English
description The crystal structure of the compound with empirical formula [Cu (2, 2'-BP)Cl NO3]2 (BP: 2,2'-bipyridine) (1) has been determined. Crystals are triclinic, space group P-1 with a = 7.5152(12) Å, b = 9.2531(14) Å, c = 10.2834(16) Å, alpha =112.181(2)º, beta = 102.155(2)º, gamma = 105.617(2)º. The copper atom displays a (4+1) square pyramidal coordination, with the four in-plane bonds provided by one chloride ion, two nitrogen atoms from the 2,2'-bipyridine molecule and one oxygen from the nitrate group. The apical position corresponds to a chloride ion Cl(1') from a centrosymmetric neighboring moiety. The two symmetry related Cl ions bridge two copper atoms, generating a dimeric unit (Cu(1)-Cl(1) = 2.2726(11) Å, Cu(1)-Cl (1') = 2.7093(13) Å). Magnetic susceptibility measurements showed a weak ferromagnetic interaction between dimers
author ATRIA,A.M.
CORTÉS,P
ACEVEDO,L
TRUJILLO,R
MANZUR,J
PEÑA,O
BAGGIO,R
spellingShingle ATRIA,A.M.
CORTÉS,P
ACEVEDO,L
TRUJILLO,R
MANZUR,J
PEÑA,O
BAGGIO,R
PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
author_facet ATRIA,A.M.
CORTÉS,P
ACEVEDO,L
TRUJILLO,R
MANZUR,J
PEÑA,O
BAGGIO,R
author_sort ATRIA,A.M.
title PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
title_short PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
title_full PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
title_fullStr PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
title_full_unstemmed PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')­COPPER(II):[Cu(2,2'-BP)Cl NO3]2
title_sort preparation, structure and properties of bis (m2-chloro)-(nitrato-o)-(2,2'-bipyridine-n.n')­copper(ii):[cu(2,2'-bp)cl no3]2
publisher Sociedad Chilena de Química
publishDate 2004
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000400013
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