Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light
Porphyrins and phthalocyanines of transition metals are good catalysts for many redox reactions [<A HREF="#1">1</A>-<A HREF="#7">7</A>]. In order to increase their catalytic activity it is often necessary to modify the macrocycle with donor or acceptor sub...
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Sociedad Chilena de Química
2005
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oai:scielo:S0717-970720050001000022005-05-27Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible lightARMIJO,FRANCISCOAGUIRRE,MARÍA JPorphyrins and phthalocyanines of transition metals are good catalysts for many redox reactions [<A HREF="#1">1</A>-<A HREF="#7">7</A>]. In order to increase their catalytic activity it is often necessary to modify the macrocycle with donor or acceptor substituents making the species more reductive or oxidant depending on the analyte. However, this process is a one-way modification, because the molecule enhances or diminishes the electronic density of the metal by the substituent effectinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.1 20052005-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100002en10.4067/S0717-97072005000100002 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
description |
Porphyrins and phthalocyanines of transition metals are good catalysts for many redox reactions [<A HREF="#1">1</A>-<A HREF="#7">7</A>]. In order to increase their catalytic activity it is often necessary to modify the macrocycle with donor or acceptor substituents making the species more reductive or oxidant depending on the analyte. However, this process is a one-way modification, because the molecule enhances or diminishes the electronic density of the metal by the substituent effect |
author |
ARMIJO,FRANCISCO AGUIRRE,MARÍA J |
spellingShingle |
ARMIJO,FRANCISCO AGUIRRE,MARÍA J Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
author_facet |
ARMIJO,FRANCISCO AGUIRRE,MARÍA J |
author_sort |
ARMIJO,FRANCISCO |
title |
Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
title_short |
Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
title_full |
Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
title_fullStr |
Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
title_full_unstemmed |
Electrocatalysis of NO2- on poly-M-tetraaminophenylporphyrines (M = Ni, Cu) modified electrodes assisted by visible light |
title_sort |
electrocatalysis of no2- on poly-m-tetraaminophenylporphyrines (m = ni, cu) modified electrodes assisted by visible light |
publisher |
Sociedad Chilena de Química |
publishDate |
2005 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100002 |
work_keys_str_mv |
AT armijofrancisco electrocatalysisofno2onpolymtetraaminophenylporphyrinesmnicumodifiedelectrodesassistedbyvisiblelight AT aguirremariaj electrocatalysisofno2onpolymtetraaminophenylporphyrinesmnicumodifiedelectrodesassistedbyvisiblelight |
_version_ |
1718445345480900608 |