Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6

The new selenophosphate phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6, stabilized by the chalcophosphate anions (P2Se6)4-, were prepared by molten polythiophosphate fluxes. The reaction products were characterized by atomic absorption (ICP) and Scanning Electron Microscopy (SEM-EDX), po...

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Autores principales:	GALDÁMEZ,A, MANRÍQUEZ,V, RUIZ,D, AVILA,R.E.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2005
Materias:	selenodiphosphates electrical properties
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100008
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spelling	oai:scielo:S0717-970720050001000082005-05-27Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6GALDÁMEZ,AMANRÍQUEZ,VRUIZ,DAVILA,R.E. selenodiphosphates electrical properties The new selenophosphate phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6, stabilized by the chalcophosphate anions (P2Se6)4-, were prepared by molten polythiophosphate fluxes. The reaction products were characterized by atomic absorption (ICP) and Scanning Electron Microscopy (SEM-EDX), powder X-ray (XRD), Fourier transform infrared spectroscopy (FTIR) and a.c. and d.c. electrical conductivity measurements. The phases A0.7Bi1.1P2Se 6 and CuBi1-X SbX P2Se 6 are structurally related to AMP2Se6 and they possess two-dimensional (2D) structure. These phases are semiconductors, with values of electrical conductivity, sI, about 10-4 W-1cm-1 at room temperatureinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.1 20052005-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100008en10.4067/S0717-97072005000100008
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	selenodiphosphates electrical properties
spellingShingle	selenodiphosphates electrical properties GALDÁMEZ,A MANRÍQUEZ,V RUIZ,D AVILA,R.E. Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
description	The new selenophosphate phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6, stabilized by the chalcophosphate anions (P2Se6)4-, were prepared by molten polythiophosphate fluxes. The reaction products were characterized by atomic absorption (ICP) and Scanning Electron Microscopy (SEM-EDX), powder X-ray (XRD), Fourier transform infrared spectroscopy (FTIR) and a.c. and d.c. electrical conductivity measurements. The phases A0.7Bi1.1P2Se 6 and CuBi1-X SbX P2Se 6 are structurally related to AMP2Se6 and they possess two-dimensional (2D) structure. These phases are semiconductors, with values of electrical conductivity, sI, about 10-4 W-1cm-1 at room temperature
author	GALDÁMEZ,A MANRÍQUEZ,V RUIZ,D AVILA,R.E.
author_facet	GALDÁMEZ,A MANRÍQUEZ,V RUIZ,D AVILA,R.E.
author_sort	GALDÁMEZ,A
title	Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
title_short	Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
title_full	Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
title_fullStr	Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
title_full_unstemmed	Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6
title_sort	physical properties of the phases a0.7bi1.1p2se 6 (a = cu, ag) and cubi1-x sbx p2se 6
publisher	Sociedad Chilena de Química
publishDate	2005
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100008
work_keys_str_mv	AT galdameza physicalpropertiesofthephasesa07bi11p2se6acuagandcubi1xsbxp2se6 AT manriquezv physicalpropertiesofthephasesa07bi11p2se6acuagandcubi1xsbxp2se6 AT ruizd physicalpropertiesofthephasesa07bi11p2se6acuagandcubi1xsbxp2se6 AT avilare physicalpropertiesofthephasesa07bi11p2se6acuagandcubi1xsbxp2se6
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Physical Properties of the Phases A0.7Bi1.1P2Se 6 (A = Cu, Ag) and CuBi1-X SbX P2Se 6

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