Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method
In this study, the preparation of nanostructured particles of metal/metal oxides by using a pyrolysis of organometallic polyphosphazenes having the metal anchored to the polymeric chain is described. The elaboration process is based on the thermal decomposition of organometallic derivatives of polyp...
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Sociedad Chilena de Química
2005
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oai:scielo:S0717-970720050001000092005-05-27Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer methodDÍAZ,CARLOSVALENZUELA,MARIA LUISA nanomaterials organometallic polymers nanoparticles solid state In this study, the preparation of nanostructured particles of metal/metal oxides by using a pyrolysis of organometallic polyphosphazenes having the metal anchored to the polymeric chain is described. The elaboration process is based on the thermal decomposition of organometallic derivatives of polyphosphazenes in air at temperature of 800 C°. As an example, the preparation of chromium, iron, ruthenium and manganese nanoclusters have been described, but the method is very general and a variety of meta/metal oxide materials can be obtained. Preliminary results on some special properties of the products are given and potential applications are discussedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.1 20052005-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100009en10.4067/S0717-97072005000100009 |
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Scielo Chile |
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Scielo Chile |
language |
English |
topic |
nanomaterials organometallic polymers nanoparticles solid state |
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nanomaterials organometallic polymers nanoparticles solid state DÍAZ,CARLOS VALENZUELA,MARIA LUISA Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
description |
In this study, the preparation of nanostructured particles of metal/metal oxides by using a pyrolysis of organometallic polyphosphazenes having the metal anchored to the polymeric chain is described. The elaboration process is based on the thermal decomposition of organometallic derivatives of polyphosphazenes in air at temperature of 800 C°. As an example, the preparation of chromium, iron, ruthenium and manganese nanoclusters have been described, but the method is very general and a variety of meta/metal oxide materials can be obtained. Preliminary results on some special properties of the products are given and potential applications are discussed |
author |
DÍAZ,CARLOS VALENZUELA,MARIA LUISA |
author_facet |
DÍAZ,CARLOS VALENZUELA,MARIA LUISA |
author_sort |
DÍAZ,CARLOS |
title |
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
title_short |
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
title_full |
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
title_fullStr |
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
title_full_unstemmed |
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
title_sort |
synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method |
publisher |
Sociedad Chilena de Química |
publishDate |
2005 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100009 |
work_keys_str_mv |
AT diazcarlos synthesisofnanostructuredmaterialsbyanewsolidstatepyrolysisorganometallicpolymermethod AT valenzuelamarialuisa synthesisofnanostructuredmaterialsbyanewsolidstatepyrolysisorganometallicpolymermethod |
_version_ |
1718445346715074560 |