Chiral Discrimination of L- and D-N-acyl-1-phenyl-d5-2-aminopropanes in a Cesium N-Dodecanoyl-L-Threoninate Cholesteric Nematic Lyomesophase

Chiral Discrimination of L- and D-N-acyl-1-phenyl-d5-2-aminopropanes in a Cesium N-Dodecanoyl-L-Threoninate Cholesteric Nematic Lyomesophase

Molecular recognition based on chirality has fundamental importance in many biological processes. Deuterium quadrupole splittings from the aromatic ring and mesophase components of two series of optical isomers, L- and D-N-acyl-1-phenyl-d5-2-aminopropanes, dissolved in anionic nematic cholesteric ly...

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Autores principales: AHUMADA,HERNÁN, MONTECINOS,RODRIGO, ALEGRÍA,SERGIO, ARAYA-MATURANA,RAMIRO, WEISS-LÓPEZ,BORIS E
Lenguaje:English
Publicado: Sociedad Chilena de Química 2005
Materias:
2H-NMR Quadrupole Splittings
Order Parameters
Chiral Discrimination
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100010
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