N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY

N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY

The easy N-functionalization of dihydrocarvone was achieved through the preparation of its imine derivatives. Secondary amines were obtained by the reduction and allylation of ketimines derived from dihydrocarvone. It was established that these amines represent mixtures of four stereoisomers which w...

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Autores principales: KOUZNETSOV,VLADÍMIR V., URBINA G.,JUAN MANUEL, STASHENKO,ELENA E.
Lenguaje:English
Publicado: Sociedad Chilena de Química 2005
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300006
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spelling oai:scielo:S0717-970720050003000062005-11-23N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDYKOUZNETSOV,VLADÍMIR V.URBINA G.,JUAN MANUELSTASHENKO,ELENA E.The easy N-functionalization of dihydrocarvone was achieved through the preparation of its imine derivatives. Secondary amines were obtained by the reduction and allylation of ketimines derived from dihydrocarvone. It was established that these amines represent mixtures of four stereoisomers which were analyzed by capillary gas chromatographic-mass spectrometry (GC-MS) (EI, 70 eV). Total energy and heat of formation for diastereoisomeric amines were calculated using AM1 and PM3 semi-empiric methodsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.3 20052005-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300006en10.4067/S0717-97072005000300006
institution Scielo Chile
collection Scielo Chile
language English
description The easy N-functionalization of dihydrocarvone was achieved through the preparation of its imine derivatives. Secondary amines were obtained by the reduction and allylation of ketimines derived from dihydrocarvone. It was established that these amines represent mixtures of four stereoisomers which were analyzed by capillary gas chromatographic-mass spectrometry (GC-MS) (EI, 70 eV). Total energy and heat of formation for diastereoisomeric amines were calculated using AM1 and PM3 semi-empiric methods
author KOUZNETSOV,VLADÍMIR V.
URBINA G.,JUAN MANUEL
STASHENKO,ELENA E.
spellingShingle KOUZNETSOV,VLADÍMIR V.
URBINA G.,JUAN MANUEL
STASHENKO,ELENA E.
N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
author_facet KOUZNETSOV,VLADÍMIR V.
URBINA G.,JUAN MANUEL
STASHENKO,ELENA E.
author_sort KOUZNETSOV,VLADÍMIR V.
title N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
title_short N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
title_full N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
title_fullStr N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
title_full_unstemmed N-FUNCTIONALIZATION OF DIHYDROCARVONE: OBTAINING AMINOCYCLOHEXANE DERIVATIVES AND THEIR SPECTROMETRIC STUDY
title_sort n-functionalization of dihydrocarvone: obtaining aminocyclohexane derivatives and their spectrometric study
publisher Sociedad Chilena de Química
publishDate 2005
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300006
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AT stashenkoelenae nfunctionalizationofdihydrocarvoneobtainingaminocyclohexanederivativesandtheirspectrometricstudy
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