CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES

In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and n...

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Autores principales:	PEREZ,F. R., BASÁEZ,L., BELMAR,J., VANYSEK,P.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2005
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300009
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spelling	oai:scielo:S0717-970720050003000092005-11-23CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXESPEREZ,F. R.BASÁEZ,L.BELMAR,J.VANYSEK,P.In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and nitridomanganese(V) complexes. The ligands have an irreversible oxidation potential of 1.1 V. Chloromanganese(III) complexes are quasi-reversible with an E1/2 of 0.1 V. Nitridomanganese(V) complexes are also quasi-reversible, with E1/2 potentials of 0.95 V. However, for nitridomanganese(V) complexes reversibility increases as the scan speed raises from 100 to 3000 mV·s-1info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.3 20052005-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300009en10.4067/S0717-97072005000300009
institution	Scielo Chile
collection	Scielo Chile
language	English
description	In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and nitridomanganese(V) complexes. The ligands have an irreversible oxidation potential of 1.1 V. Chloromanganese(III) complexes are quasi-reversible with an E1/2 of 0.1 V. Nitridomanganese(V) complexes are also quasi-reversible, with E1/2 potentials of 0.95 V. However, for nitridomanganese(V) complexes reversibility increases as the scan speed raises from 100 to 3000 mV·s-1
author	PEREZ,F. R. BASÁEZ,L. BELMAR,J. VANYSEK,P.
spellingShingle	PEREZ,F. R. BASÁEZ,L. BELMAR,J. VANYSEK,P. CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
author_facet	PEREZ,F. R. BASÁEZ,L. BELMAR,J. VANYSEK,P.
author_sort	PEREZ,F. R.
title	CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
title_short	CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
title_full	CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
title_fullStr	CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
title_full_unstemmed	CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
title_sort	cyclic voltammetry of 1-(n-hexyl)-3-methyl-5-pyrazolone-based enamines and their chloromanganese(iii) and nitridomanganese(v) complexes
publisher	Sociedad Chilena de Química
publishDate	2005
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300009
work_keys_str_mv	AT perezfr cyclicvoltammetryof1nhexyl3methyl5pyrazolonebasedenaminesandtheirchloromanganeseiiiandnitridomanganesevcomplexes AT basaezl cyclicvoltammetryof1nhexyl3methyl5pyrazolonebasedenaminesandtheirchloromanganeseiiiandnitridomanganesevcomplexes AT belmarj cyclicvoltammetryof1nhexyl3methyl5pyrazolonebasedenaminesandtheirchloromanganeseiiiandnitridomanganesevcomplexes AT vanysekp cyclicvoltammetryof1nhexyl3methyl5pyrazolonebasedenaminesandtheirchloromanganeseiiiandnitridomanganesevcomplexes
_version_	1718445351808008192

CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES

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