REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES

The catalysis of the hydroesterification and hydroformylation-acetalization of 1-hexene by rhodium(I), cis-[Rh(CO)2(amine)2](PF6) complexes (amine = pyridine, 2-picoline, 3-picoline, 4-picoline, 3,5-lutidine or 2,6-lutidine) dissolved in 10 mL of ethanol or 10 mL of 80% aqueous ethanol, 0.4 mL (3 x...

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Autores principales:	UZCÁTEGUI,G. C., HUNG,F., ORTEGA,M. C., PARDEY,A. J., LONGO,C., AGUIRRE,P., MOYA,S. A.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2005
Materias:	Catalysis Reppe reaction rhodium complexes 1-hexene
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400003
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id	oai:scielo:S0717-97072005000400003
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spelling	oai:scielo:S0717-970720050004000032006-04-19REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXESUZCÁTEGUI,G. C.HUNG,F.ORTEGA,M. C.PARDEY,A. J.LONGO,C.AGUIRRE,P.MOYA,S. A. Catalysis Reppe reaction rhodium complexes 1-hexene The catalysis of the hydroesterification and hydroformylation-acetalization of 1-hexene by rhodium(I), cis-[Rh(CO)2(amine)2](PF6) complexes (amine = pyridine, 2-picoline, 3-picoline, 4-picoline, 3,5-lutidine or 2,6-lutidine) dissolved in 10 mL of ethanol or 10 mL of 80% aqueous ethanol, 0.4 mL (3 x 10-3 mol) of 1-hexene, [Rh] = 5 x 10-5 mol, 1-hexene/Rh = 64 under P(CO) = 0.9 atm at 100 °C for 4 h, is described in this work. The mayor products are ethyl-heptanoate, heptanal and 1,1-diethoxyheptane coming from the hydroesterification, hydroformylation reactions and the nucleophilic addition reaction of the ethanol over the formed heptanal, respectively. The reaction product distribution depends on the nature of the coordinate amine to the rhodium centerinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.4 20052005-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400003en10.4067/S0717-97072005000400003
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Catalysis Reppe reaction rhodium complexes 1-hexene
spellingShingle	Catalysis Reppe reaction rhodium complexes 1-hexene UZCÁTEGUI,G. C. HUNG,F. ORTEGA,M. C. PARDEY,A. J. LONGO,C. AGUIRRE,P. MOYA,S. A. REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
description	The catalysis of the hydroesterification and hydroformylation-acetalization of 1-hexene by rhodium(I), cis-[Rh(CO)2(amine)2](PF6) complexes (amine = pyridine, 2-picoline, 3-picoline, 4-picoline, 3,5-lutidine or 2,6-lutidine) dissolved in 10 mL of ethanol or 10 mL of 80% aqueous ethanol, 0.4 mL (3 x 10-3 mol) of 1-hexene, [Rh] = 5 x 10-5 mol, 1-hexene/Rh = 64 under P(CO) = 0.9 atm at 100 °C for 4 h, is described in this work. The mayor products are ethyl-heptanoate, heptanal and 1,1-diethoxyheptane coming from the hydroesterification, hydroformylation reactions and the nucleophilic addition reaction of the ethanol over the formed heptanal, respectively. The reaction product distribution depends on the nature of the coordinate amine to the rhodium center
author	UZCÁTEGUI,G. C. HUNG,F. ORTEGA,M. C. PARDEY,A. J. LONGO,C. AGUIRRE,P. MOYA,S. A.
author_facet	UZCÁTEGUI,G. C. HUNG,F. ORTEGA,M. C. PARDEY,A. J. LONGO,C. AGUIRRE,P. MOYA,S. A.
author_sort	UZCÁTEGUI,G. C.
title	REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
title_short	REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
title_full	REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
title_fullStr	REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
title_full_unstemmed	REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
title_sort	reppe reaction catalyzed by soluble carbonylrhodium complexes
publisher	Sociedad Chilena de Química
publishDate	2005
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400003
work_keys_str_mv	AT uzcateguigc reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT hungf reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT ortegamc reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT pardeyaj reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT longoc reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT aguirrep reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes AT moyasa reppereactioncatalyzedbysolublecarbonylrhodiumcomplexes
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REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES

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