CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2

Activated carbons of high adsorbents properties for adsorption of chromium species from aqueous solution and Tannery effluents were prepared from coconut shells by means of chemical activation using as activating agents the KOH and ZnCL2, in atmosphere of N2(g) and CO2(g), respectively. It was found...

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Autores principales: BENDEZÚ,S., OYAGUE,J., ROMERO,A., GARCÍA,R., MUÑOZ,Y., ESCALON,N.
Lenguaje:English
Publicado: Sociedad Chilena de Química 2005
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400007
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spelling oai:scielo:S0717-970720050004000072006-04-19CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2BENDEZÚ,S.OYAGUE,J.ROMERO,A.GARCÍA,R.MUÑOZ,Y.ESCALON,N. Activated carbon Activation, Chemical treatment Adsorption Adsorption properties Microporous adsorbents Activated carbons of high adsorbents properties for adsorption of chromium species from aqueous solution and Tannery effluents were prepared from coconut shells by means of chemical activation using as activating agents the KOH and ZnCL2, in atmosphere of N2(g) and CO2(g), respectively. It was found that the adsorption capacity of the produced activated carbons are significantly higher than that of the commercial one that was tested. Based on the results obtained from a variety of characterization methods, it has been determined the presence of functional organic groups, phenols and carbonyls, which are responsible for the activated carbons surface charge and it favored the chromium species adsorption, zeta potential measurements helped to explain the metal adsorption in terms of electrostatic attraction-repulsion behavior of the activated carbon surface and cations of Cr(III) and oxyanions of Cr(VI), respectively. It was observed that the activated carbons CK12 and CZ32 displayed the biggest adsorbents properties, it was adsorbed approximately 721.38 mg of chromium with the CK12, 534.43 mg with the CZ32, and only 274.02 mg with the commercial carbon (CC), by gram of activated carbon, respectively, at pH 4.45 from Tannery effluentsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.4 20052005-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400007en10.4067/S0717-97072005000400007
institution Scielo Chile
collection Scielo Chile
language English
topic Activated carbon
Activation, Chemical treatment
Adsorption
Adsorption properties
Microporous adsorbents
spellingShingle Activated carbon
Activation, Chemical treatment
Adsorption
Adsorption properties
Microporous adsorbents
BENDEZÚ,S.
OYAGUE,J.
ROMERO,A.
GARCÍA,R.
MUÑOZ,Y.
ESCALON,N.
CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
description Activated carbons of high adsorbents properties for adsorption of chromium species from aqueous solution and Tannery effluents were prepared from coconut shells by means of chemical activation using as activating agents the KOH and ZnCL2, in atmosphere of N2(g) and CO2(g), respectively. It was found that the adsorption capacity of the produced activated carbons are significantly higher than that of the commercial one that was tested. Based on the results obtained from a variety of characterization methods, it has been determined the presence of functional organic groups, phenols and carbonyls, which are responsible for the activated carbons surface charge and it favored the chromium species adsorption, zeta potential measurements helped to explain the metal adsorption in terms of electrostatic attraction-repulsion behavior of the activated carbon surface and cations of Cr(III) and oxyanions of Cr(VI), respectively. It was observed that the activated carbons CK12 and CZ32 displayed the biggest adsorbents properties, it was adsorbed approximately 721.38 mg of chromium with the CK12, 534.43 mg with the CZ32, and only 274.02 mg with the commercial carbon (CC), by gram of activated carbon, respectively, at pH 4.45 from Tannery effluents
author BENDEZÚ,S.
OYAGUE,J.
ROMERO,A.
GARCÍA,R.
MUÑOZ,Y.
ESCALON,N.
author_facet BENDEZÚ,S.
OYAGUE,J.
ROMERO,A.
GARCÍA,R.
MUÑOZ,Y.
ESCALON,N.
author_sort BENDEZÚ,S.
title CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
title_short CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
title_full CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
title_fullStr CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
title_full_unstemmed CHROMIUM ADSORPTION FROM TANNERY EFFLUENTS BY ACTIVATED CARBONS PREPARED FROM COCONUT SHELLS BY CHEMICAL ACTIVATION WITH KOH AND ZNCL2
title_sort chromium adsorption from tannery effluents by activated carbons prepared from coconut shells by chemical activation with koh and zncl2
publisher Sociedad Chilena de Química
publishDate 2005
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000400007
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