POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS

POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS

Polychelates of poly(4-vinyl pyridine) with metal acetates of Cu(II) and Zn(II) are synthesized. These compounds are characterized by elemental and thermal analysis, FT-IR and electronic spectroscopies in the d-d region of the spectrum. The influence of the nitrogen polymer ligand on the structure o...

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Autores principales: SEGUEL,GLORIA V, RIVAS,BERNABÉ L, NOVAS,CLAUDIA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2006
Materias:
metal ions
semi-empirical calculations
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100009
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spelling oai:scielo:S0717-970720060001000092006-06-08POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONSSEGUEL,GLORIA VRIVAS,BERNABÉ LNOVAS,CLAUDIA metal ions semi-empirical calculations Polychelates of poly(4-vinyl pyridine) with metal acetates of Cu(II) and Zn(II) are synthesized. These compounds are characterized by elemental and thermal analysis, FT-IR and electronic spectroscopies in the d-d region of the spectrum. The influence of the nitrogen polymer ligand on the structure of metal acetates is studied. Semi-empirical calculations by PM3 method are done. To that the most stable polymer ligand conformations of the polychelates are employed. The electrostatic potential of the most stable polychelate structures is calculatedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.1 20062006-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100009en10.4067/S0717-97072006000100009
institution Scielo Chile
collection Scielo Chile
language English
topic metal ions
semi-empirical calculations
spellingShingle metal ions
semi-empirical calculations
SEGUEL,GLORIA V
RIVAS,BERNABÉ L
NOVAS,CLAUDIA
POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
description Polychelates of poly(4-vinyl pyridine) with metal acetates of Cu(II) and Zn(II) are synthesized. These compounds are characterized by elemental and thermal analysis, FT-IR and electronic spectroscopies in the d-d region of the spectrum. The influence of the nitrogen polymer ligand on the structure of metal acetates is studied. Semi-empirical calculations by PM3 method are done. To that the most stable polymer ligand conformations of the polychelates are employed. The electrostatic potential of the most stable polychelate structures is calculated
author SEGUEL,GLORIA V
RIVAS,BERNABÉ L
NOVAS,CLAUDIA
author_facet SEGUEL,GLORIA V
RIVAS,BERNABÉ L
NOVAS,CLAUDIA
author_sort SEGUEL,GLORIA V
title POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
title_short POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
title_full POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
title_fullStr POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
title_full_unstemmed POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
title_sort polychelates of poly(4-vinylpyridine) with cu(ii) and zn(ii): synthesis,characterization, and semi-empirica calculations
publisher Sociedad Chilena de Química
publishDate 2006
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100009
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AT rivasbernabel polychelatesofpoly4vinylpyridinewithcuiiandzniisynthesischaracterizationandsemiempiricacalculations
AT novasclaudia polychelatesofpoly4vinylpyridinewithcuiiandzniisynthesischaracterizationandsemiempiricacalculations
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