REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY
This paper describes the catalytic activation studies of the reduction of some 2-substituted-5-nitrofuran compounds by [Rh(COD)(2-picoline)2](PF6) (COD = 1,5-cyclooctadiene) anchored on poly(4-vinylpyridine) in contact with 80% aqueous 2-ethoxyethanol at 100 º C under carbon monoxide atmosphere. The...
Guardado en:
| Autores principales: | , , , , , , , , |
|---|---|
| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2006
|
| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100014 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| id |
oai:scielo:S0717-97072006000100014 |
|---|---|
| record_format |
dspace |
| spelling |
oai:scielo:S0717-970720060001000142006-06-08REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITYFARKAS,M. E.RODRÍGUEZ,ELONGO,CMONASTERIOS,MORTEGA,M. C.RIVAS,A. B.PARDEY,A. J.LÓPEZ,RMOYA,S.A. Rhodium complexes Poly (4-vinylpyridine) Carbon monoxide Water Reduction This paper describes the catalytic activation studies of the reduction of some 2-substituted-5-nitrofuran compounds by [Rh(COD)(2-picoline)2](PF6) (COD = 1,5-cyclooctadiene) anchored on poly(4-vinylpyridine) in contact with 80% aqueous 2-ethoxyethanol at 100 º C under carbon monoxide atmosphere. The effect of varying the nature of the 2-substituents of the furan ring was evaluated. The importance of the present catalysis studies can be emphasized, because the potential activity against bacteria of the 2-substituted-5-nitrofuran compounds could be monitored by determining the facility of catalytic reduction of the nitro groupinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.1 20062006-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100014en10.4067/S0717-97072006000100014 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Rhodium complexes Poly (4-vinylpyridine) Carbon monoxide Water Reduction |
| spellingShingle |
Rhodium complexes Poly (4-vinylpyridine) Carbon monoxide Water Reduction FARKAS,M. E. RODRÍGUEZ,E LONGO,C MONASTERIOS,M ORTEGA,M. C. RIVAS,A. B. PARDEY,A. J. LÓPEZ,R MOYA,S.A. REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| description |
This paper describes the catalytic activation studies of the reduction of some 2-substituted-5-nitrofuran compounds by [Rh(COD)(2-picoline)2](PF6) (COD = 1,5-cyclooctadiene) anchored on poly(4-vinylpyridine) in contact with 80% aqueous 2-ethoxyethanol at 100 º C under carbon monoxide atmosphere. The effect of varying the nature of the 2-substituents of the furan ring was evaluated. The importance of the present catalysis studies can be emphasized, because the potential activity against bacteria of the 2-substituted-5-nitrofuran compounds could be monitored by determining the facility of catalytic reduction of the nitro group |
| author |
FARKAS,M. E. RODRÍGUEZ,E LONGO,C MONASTERIOS,M ORTEGA,M. C. RIVAS,A. B. PARDEY,A. J. LÓPEZ,R MOYA,S.A. |
| author_facet |
FARKAS,M. E. RODRÍGUEZ,E LONGO,C MONASTERIOS,M ORTEGA,M. C. RIVAS,A. B. PARDEY,A. J. LÓPEZ,R MOYA,S.A. |
| author_sort |
FARKAS,M. E. |
| title |
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| title_short |
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| title_full |
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| title_fullStr |
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| title_full_unstemmed |
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY |
| title_sort |
reduction of 5-nitrofuran compounds catalyzed by a rhodium complex immobilized on poly(4-vinylpyridine): a relationship with antibacterial activity |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2006 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000100014 |
| work_keys_str_mv |
AT farkasme reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT rodrigueze reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT longoc reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT monasteriosm reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT ortegamc reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT rivasab reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT pardeyaj reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT lopezr reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity AT moyasa reductionof5nitrofurancompoundscatalyzedbyarhodiumcompleximmobilizedonpoly4vinylpyridinearelationshipwithantibacterialactivity |
| _version_ |
1718445359030599680 |