CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O)
The ionic cobalt (II) title complex [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) (where Ac: Acetate, Bipy: 2,2-bipyridine) consists of anionic bimetallic unit in which cobalt ions are bridged by hydroxo and acetate ligands, balanced by a (disordered) potassium cation. The geometry at cobalt is distorted octahe...
Guardado en:
| Autores principales: | , , , , , |
|---|---|
| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2006
|
| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200002 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| id |
oai:scielo:S0717-97072006000200002 |
|---|---|
| record_format |
dspace |
| spelling |
oai:scielo:S0717-970720060002000022006-06-30CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O)CORTES,P.ATRIA,A. M.GARLAND,M. T.BAGGIO,R.PEÑA,O.CORSINI,G. cobalt crystal structure antibacterial activities The ionic cobalt (II) title complex [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) (where Ac: Acetate, Bipy: 2,2-bipyridine) consists of anionic bimetallic unit in which cobalt ions are bridged by hydroxo and acetate ligands, balanced by a (disordered) potassium cation. The geometry at cobalt is distorted octahedral with the O atoms of a monodentate and a bridging acetate groups occupying the apical sites and O atoms from the hydroxo groups and N atoms from Bipy, the equatorial sites in each cobalt coordination sphere. Magnetic susceptibility data of powdered samples of the compound are presented. The antimicrobial activities of the complex has been screened in vitro against the microorganisms Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia coliinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.2 20062006-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200002en10.4067/S0717-97072006000200002 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
cobalt crystal structure antibacterial activities |
| spellingShingle |
cobalt crystal structure antibacterial activities CORTES,P. ATRIA,A. M. GARLAND,M. T. BAGGIO,R. PEÑA,O. CORSINI,G. CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| description |
The ionic cobalt (II) title complex [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) (where Ac: Acetate, Bipy: 2,2-bipyridine) consists of anionic bimetallic unit in which cobalt ions are bridged by hydroxo and acetate ligands, balanced by a (disordered) potassium cation. The geometry at cobalt is distorted octahedral with the O atoms of a monodentate and a bridging acetate groups occupying the apical sites and O atoms from the hydroxo groups and N atoms from Bipy, the equatorial sites in each cobalt coordination sphere. Magnetic susceptibility data of powdered samples of the compound are presented. The antimicrobial activities of the complex has been screened in vitro against the microorganisms Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia coli |
| author |
CORTES,P. ATRIA,A. M. GARLAND,M. T. BAGGIO,R. PEÑA,O. CORSINI,G. |
| author_facet |
CORTES,P. ATRIA,A. M. GARLAND,M. T. BAGGIO,R. PEÑA,O. CORSINI,G. |
| author_sort |
CORTES,P. |
| title |
CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| title_short |
CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| title_full |
CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| title_fullStr |
CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| title_full_unstemmed |
CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF A HIGH SPIN COBALT(II) DIMER: [Co2(OH)2 (Ac)3(Bipy)2]·K ·2(H2O) |
| title_sort |
crystal structure and antimicrobial activity of a high spin cobalt(ii) dimer: [co2(oh)2 (ac)3(bipy)2]·k ·2(h2o) |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2006 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200002 |
| work_keys_str_mv |
AT cortesp crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o AT atriaam crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o AT garlandmt crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o AT baggior crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o AT penao crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o AT corsinig crystalstructureandantimicrobialactivityofahighspincobaltiidimerco2oh2ac3bipy2k2h2o |
| _version_ |
1718445359377678336 |