REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS

This paper describes a combined synthesis of b-hydroxy-sesquiterpen eudesmane derivative using a microbiological hydroxylation sesquiterpen eudesmane derivative as the key reaction. The stereochemistry of the biohydroxylation was identified using mono and bi-dimensional ¹H-NMR experiments

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Autores principales: ÁGUILA,SERGIO, ALARCÓN,JULIO, CONEJEROS,CAROLINA, ALDERETE,JOEL B
Lenguaje:English
Publicado: Sociedad Chilena de Química 2006
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200004
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spelling oai:scielo:S0717-970720060002000042006-06-30REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANSÁGUILA,SERGIOALARCÓN,JULIOCONEJEROS,CAROLINAALDERETE,JOEL B Biotransformation Sesquiterpenes Stereoselective Hydroxylation Agarofurans This paper describes a combined synthesis of b-hydroxy-sesquiterpen eudesmane derivative using a microbiological hydroxylation sesquiterpen eudesmane derivative as the key reaction. The stereochemistry of the biohydroxylation was identified using mono and bi-dimensional ¹H-NMR experimentsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.2 20062006-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200004en10.4067/S0717-97072006000200004
institution Scielo Chile
collection Scielo Chile
language English
topic Biotransformation
Sesquiterpenes
Stereoselective Hydroxylation
Agarofurans
spellingShingle Biotransformation
Sesquiterpenes
Stereoselective Hydroxylation
Agarofurans
ÁGUILA,SERGIO
ALARCÓN,JULIO
CONEJEROS,CAROLINA
ALDERETE,JOEL B
REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
description This paper describes a combined synthesis of b-hydroxy-sesquiterpen eudesmane derivative using a microbiological hydroxylation sesquiterpen eudesmane derivative as the key reaction. The stereochemistry of the biohydroxylation was identified using mono and bi-dimensional ¹H-NMR experiments
author ÁGUILA,SERGIO
ALARCÓN,JULIO
CONEJEROS,CAROLINA
ALDERETE,JOEL B
author_facet ÁGUILA,SERGIO
ALARCÓN,JULIO
CONEJEROS,CAROLINA
ALDERETE,JOEL B
author_sort ÁGUILA,SERGIO
title REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
title_short REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
title_full REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
title_fullStr REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
title_full_unstemmed REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS
title_sort regio and stereoselective hydroxylation of 5a-hydroxy-14-eudesm-11-en-3-one eudesmane by biotransformation of rhizopus nigricans
publisher Sociedad Chilena de Química
publishDate 2006
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200004
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