SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS

Reaction of the chiral compound (S)-(+)-BrCH2CHMeCH2OH with Ph2PK in the presence of lithium diisopropylamide (LDA) and BH3/THF yields the monophosphine (S)-Ph2P(BH3)CH2CHMeCH 2OH(1). The reaction of 1 with ClOSO2Me/Et3N or NaH/MeI gives rise to the formation of the general compound (S)-Ph2P(BH3)CH2...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	DIAZ,OSCAR, CONTRERAS,RAUL, VALDERRAMA,MAURICIO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2006
Materias:	Iridium chiral ligands chiral phiosphine hemilabile ligands
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200008
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072006000200008
record_format	dspace
spelling	oai:scielo:S0717-970720060002000082006-06-30SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDSDIAZ,OSCARCONTRERAS,RAULVALDERRAMA,MAURICIO Iridium chiral ligands chiral phiosphine hemilabile ligands Reaction of the chiral compound (S)-(+)-BrCH2CHMeCH2OH with Ph2PK in the presence of lithium diisopropylamide (LDA) and BH3/THF yields the monophosphine (S)-Ph2P(BH3)CH2CHMeCH 2OH(1). The reaction of 1 with ClOSO2Me/Et3N or NaH/MeI gives rise to the formation of the general compound (S)-Ph2P(BH3)CH2CHMeCH 2OR [CpIrCl2(PPh2CH2CHMeCH 2OR-P)], which by treatment with pyrrolidine affords (S)-Ph2PCH2CHMeCH2 OR [R = SO2Me (4), Me (6)]. The monophophines 4, 6 and (S)-PPh2CH2CHMeCH2 OH react with [{CpIrCl(µ-Cl)}2] to give the neutral compounds [CpIrCl2(PPh2CH2CHMeCH 2OR-P)], where only the compound with R = H (7) was fully characterized. Complex 7 reacts with AgBF4 yielding the cationic complex [CpIrCl(PPh2CH2CHMeCH2 OH-P,O)]BF4 (8) in which the ligand acts in its bidentate form. Similar synthetic results were obtained using [{Cp*IrI(µ-I)}2] as starting complex .info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.2 20062006-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200008en10.4067/S0717-97072006000200008
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Iridium chiral ligands chiral phiosphine hemilabile ligands
spellingShingle	Iridium chiral ligands chiral phiosphine hemilabile ligands DIAZ,OSCAR CONTRERAS,RAUL VALDERRAMA,MAURICIO SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
description	Reaction of the chiral compound (S)-(+)-BrCH2CHMeCH2OH with Ph2PK in the presence of lithium diisopropylamide (LDA) and BH3/THF yields the monophosphine (S)-Ph2P(BH3)CH2CHMeCH 2OH(1). The reaction of 1 with ClOSO2Me/Et3N or NaH/MeI gives rise to the formation of the general compound (S)-Ph2P(BH3)CH2CHMeCH 2OR [CpIrCl2(PPh2CH2CHMeCH 2OR-P)], which by treatment with pyrrolidine affords (S)-Ph2PCH2CHMeCH2 OR [R = SO2Me (4), Me (6)]. The monophophines 4, 6 and (S)-PPh2CH2CHMeCH2 OH react with [{CpIrCl(µ-Cl)}2] to give the neutral compounds [CpIrCl2(PPh2CH2CHMeCH 2OR-P)], where only the compound with R = H (7) was fully characterized. Complex 7 reacts with AgBF4 yielding the cationic complex [CpIrCl(PPh2CH2CHMeCH2 OH-P,O)]BF4 (8) in which the ligand acts in its bidentate form. Similar synthetic results were obtained using [{Cp*IrI(µ-I)}2] as starting complex .
author	DIAZ,OSCAR CONTRERAS,RAUL VALDERRAMA,MAURICIO
author_facet	DIAZ,OSCAR CONTRERAS,RAUL VALDERRAMA,MAURICIO
author_sort	DIAZ,OSCAR
title	SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
title_short	SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
title_full	SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
title_fullStr	SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
title_full_unstemmed	SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS
title_sort	synthesis and coordination properties of chiral bidentate p,o-donor ligands
publisher	Sociedad Chilena de Química
publishDate	2006
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000200008
work_keys_str_mv	AT diazoscar synthesisandcoordinationpropertiesofchiralbidentatepodonorligands AT contrerasraul synthesisandcoordinationpropertiesofchiralbidentatepodonorligands AT valderramamauricio synthesisandcoordinationpropertiesofchiralbidentatepodonorligands
_version_	1718445360460857344

SYNTHESIS AND COORDINATION PROPERTIES OF CHIRAL BIDENTATE P,O-DONOR LIGANDS

Ejemplares similares