BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES

The miscibility in blends containing poly(methyl methacrylate-co-methacrylic acid) [P(MMA-co-MA)] as polymer component and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methyllendiphenol (MDP) as low molecular weight compounds (LMWC) was studied by Differential Scanning Calorimetry...

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Autores principales:	GATICA,NICOLÁS, ALVARADO,NANCY, SEPÚLVEDA,DANIELA
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2006
Materias:	blends poly(methyl methacrylate-co-methacrylic) ,4'-thiodiphenol 4,4'-methyllendiphenol hydrogen bond low molecular weight compounds
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300003
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spelling	oai:scielo:S0717-970720060003000032006-11-16BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIESGATICA,NICOLÁSALVARADO,NANCYSEPÚLVEDA,DANIELA blends poly(methyl methacrylate-co-methacrylic) ,4'-thiodiphenol 4,4'-methyllendiphenol hydrogen bond low molecular weight compounds The miscibility in blends containing poly(methyl methacrylate-co-methacrylic acid) [P(MMA-co-MA)] as polymer component and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methyllendiphenol (MDP) as low molecular weight compounds (LMWC) was studied by Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectrophotometry (FTIR). Thermal properties, such as the glass transition of P(MMA-co-MA) and the melting of the LMWC, were found to be clearly affected when the compounds were blended, which was attributed to the miscibility between them. FTIR was used to investigate the specific interactions between P(MMA-co-MA) and the LMWC. The formation of intermolecular hydrogen bonds between the carbonyl groups of P(MMA-co-MA) and the hydroxyl groups of TDP and MDP were discovered. Thermogravimetric and viscometry analysis were also used as additional techniques to complement the obtained FTIR and DCS resultsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.3 20062006-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300003en10.4067/S0717-97072006000300003
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	blends poly(methyl methacrylate-co-methacrylic) ,4'-thiodiphenol 4,4'-methyllendiphenol hydrogen bond low molecular weight compounds
spellingShingle	blends poly(methyl methacrylate-co-methacrylic) ,4'-thiodiphenol 4,4'-methyllendiphenol hydrogen bond low molecular weight compounds GATICA,NICOLÁS ALVARADO,NANCY SEPÚLVEDA,DANIELA BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
description	The miscibility in blends containing poly(methyl methacrylate-co-methacrylic acid) [P(MMA-co-MA)] as polymer component and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methyllendiphenol (MDP) as low molecular weight compounds (LMWC) was studied by Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectrophotometry (FTIR). Thermal properties, such as the glass transition of P(MMA-co-MA) and the melting of the LMWC, were found to be clearly affected when the compounds were blended, which was attributed to the miscibility between them. FTIR was used to investigate the specific interactions between P(MMA-co-MA) and the LMWC. The formation of intermolecular hydrogen bonds between the carbonyl groups of P(MMA-co-MA) and the hydroxyl groups of TDP and MDP were discovered. Thermogravimetric and viscometry analysis were also used as additional techniques to complement the obtained FTIR and DCS results
author	GATICA,NICOLÁS ALVARADO,NANCY SEPÚLVEDA,DANIELA
author_facet	GATICA,NICOLÁS ALVARADO,NANCY SEPÚLVEDA,DANIELA
author_sort	GATICA,NICOLÁS
title	BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
title_short	BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
title_full	BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
title_fullStr	BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
title_full_unstemmed	BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES
title_sort	blends of poly(methyl methacrylate-co-methacrylic acid) and two dihydric phenols: thermal and infrared spectroscopic studies
publisher	Sociedad Chilena de Química
publishDate	2006
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300003
work_keys_str_mv	AT gaticanicolas blendsofpolymethylmethacrylatecomethacrylicacidandtwodihydricphenolsthermalandinfraredspectroscopicstudies AT alvaradonancy blendsofpolymethylmethacrylatecomethacrylicacidandtwodihydricphenolsthermalandinfraredspectroscopicstudies AT sepulvedadaniela blendsofpolymethylmethacrylatecomethacrylicacidandtwodihydricphenolsthermalandinfraredspectroscopicstudies
_version_	1718445362829590528

BLENDS OF POLY(METHYL METHACRYLATE-CO-METHACRYLIC ACID) AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES

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