KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM

The oxidation of 6-Aminocaproic acid by Ag(III) complex, dihydroxydiperiodatoargentate(III) (DPA), was studied in alkaline medium. The reaction was first order with respect to Ag(III) complex, and the order with respect to 6-aminocaproic acid was from one to two. A plausible mechanism involving a pr...

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Autores principales:	HUO,SHUYING, SONG,CHANGYING, HUAN,SHANJIN, SHEN,SHIGANG, SUN,HANWEN
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2007
Materias:	dihydroxydiperiodatoargentate (III) 6-aminocaproic acid redox reaction kinetics and mechanism
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000100011
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spelling	oai:scielo:S0717-970720070001000112007-05-07KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUMHUO,SHUYINGSONG,CHANGYINGHUAN,SHANJINSHEN,SHIGANGSUN,HANWEN dihydroxydiperiodatoargentate (III) 6-aminocaproic acid redox reaction kinetics and mechanism The oxidation of 6-Aminocaproic acid by Ag(III) complex, dihydroxydiperiodatoargentate(III) (DPA), was studied in alkaline medium. The reaction was first order with respect to Ag(III) complex, and the order with respect to 6-aminocaproic acid was from one to two. A plausible mechanism involving a pre-equilibrium of adduct formation between the complex and reductant was proposed form the kinetics study. The rate equations derived from mechanism can explain all experimental phenomena, and the activation parameters along with rate constants of the rate-determining step were calculatedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.1 20072007-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000100011en10.4067/S0717-97072007000100011
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	dihydroxydiperiodatoargentate (III) 6-aminocaproic acid redox reaction kinetics and mechanism
spellingShingle	dihydroxydiperiodatoargentate (III) 6-aminocaproic acid redox reaction kinetics and mechanism HUO,SHUYING SONG,CHANGYING HUAN,SHANJIN SHEN,SHIGANG SUN,HANWEN KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
description	The oxidation of 6-Aminocaproic acid by Ag(III) complex, dihydroxydiperiodatoargentate(III) (DPA), was studied in alkaline medium. The reaction was first order with respect to Ag(III) complex, and the order with respect to 6-aminocaproic acid was from one to two. A plausible mechanism involving a pre-equilibrium of adduct formation between the complex and reductant was proposed form the kinetics study. The rate equations derived from mechanism can explain all experimental phenomena, and the activation parameters along with rate constants of the rate-determining step were calculated
author	HUO,SHUYING SONG,CHANGYING HUAN,SHANJIN SHEN,SHIGANG SUN,HANWEN
author_facet	HUO,SHUYING SONG,CHANGYING HUAN,SHANJIN SHEN,SHIGANG SUN,HANWEN
author_sort	HUO,SHUYING
title	KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
title_short	KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
title_full	KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
title_fullStr	KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
title_full_unstemmed	KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
title_sort	kinetics and mechanism of oxidation of 6-aminocaproic acid by dihydroxydiperiodatoa rgentate (iii) in alkaline medium
publisher	Sociedad Chilena de Química
publishDate	2007
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000100011
work_keys_str_mv	AT huoshuying kineticsandmechanismofoxidationof6aminocaproicacidbydihydroxydiperiodatoargentateiiiinalkalinemedium AT songchangying kineticsandmechanismofoxidationof6aminocaproicacidbydihydroxydiperiodatoargentateiiiinalkalinemedium AT huanshanjin kineticsandmechanismofoxidationof6aminocaproicacidbydihydroxydiperiodatoargentateiiiinalkalinemedium AT shenshigang kineticsandmechanismofoxidationof6aminocaproicacidbydihydroxydiperiodatoargentateiiiinalkalinemedium AT sunhanwen kineticsandmechanismofoxidationof6aminocaproicacidbydihydroxydiperiodatoargentateiiiinalkalinemedium
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KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM

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