WAVELENGTH AND LIGAND PERIPHERAL GROUPS EFFECTS IN PHOTOREDOX CHEMISTRY OF [FE(R-SALEN)(BR-KOJI)] COMPLEXES (SALEN = N,N’-ETHYLENEBIS(R-SALICYLIDENEIMINATO); KOJI = 5-HYDROXY-2-(HYDROXYMETHYL)-4H-PYRAN-4-ONE)

WAVELENGTH AND LIGAND PERIPHERAL GROUPS EFFECTS IN PHOTOREDOX CHEMISTRY OF [FE(R-SALEN)(BR-KOJI)] COMPLEXES (SALEN = N,N’-ETHYLENEBIS(R-SALICYLIDENEIMINATO); KOJI = 5-HYDROXY-2-(HYDROXYMETHYL)-4H-PYRAN-4-ONE)

Photoredox reactions occurring in irradiated methanolic solutions of the complexes [Fe(R-salen)(Br-koji)], (where R-salen²~ are N,N’-ethylenebis(R-salicylideneiminato) ligands (R = H, 5-F, 5-C1, 5-Br, 3-OCH3, 4-OCH3 or 5-OCH3); Br-kojr is the anión of 5-hydroxy-2-(bromomethyl)-4H-pyran-4-one) have b...

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Autor principal: ŠIMA,JOZEF
Lenguaje:English
Publicado: Sociedad Chilena de Química 2007
Materias:
complexes
salen-type ligands
bromokojato ligand
photoredox reactions
mechanism
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000100016
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