STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES

Cross-linked copolymers of acrylamide (AAm) with N-[3-(dimethyl amine)propyl]methacrylamide (NDAPM) were prepared by solution free radical polymerization at different feed molar ratios. In this reaction, ammonium persulfate (APS) and N,N´-methylene-bis-acrylamide (MBA) were used as initiator and cro...

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Autores principales:	POOLEY,S. AMALIA, RIVAS,BERNABÉ L., RIQUELME,FRANCISCO J.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2007
Materias:	copolymerization gels swelling crosslinking network
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200009
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id	oai:scielo:S0717-97072007000200009
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spelling	oai:scielo:S0717-970720070002000092007-09-13STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIESPOOLEY,S. AMALIARIVAS,BERNABÉ L.RIQUELME,FRANCISCO J. copolymerization gels swelling crosslinking network Cross-linked copolymers of acrylamide (AAm) with N-[3-(dimethyl amine)propyl]methacrylamide (NDAPM) were prepared by solution free radical polymerization at different feed molar ratios. In this reaction, ammonium persulfate (APS) and N,N´-methylene-bis-acrylamide (MBA) were used as initiator and cross-linking reagents respectively. The effects of reaction parameters, including the concentration of crosslinking reagent and initiator, the monomer concentration, pH, temperature, the various salt solutions, and solvent polarity, on the water absorption have been investigated. The results indicate that the copolymers obtained are stimuli-responsive hydrogels that change their volume and elasticity in depending on the properties of the liquid phaseinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.2 20072007-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200009en10.4067/S0717-97072007000200009
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	copolymerization gels swelling crosslinking network
spellingShingle	copolymerization gels swelling crosslinking network POOLEY,S. AMALIA RIVAS,BERNABÉ L. RIQUELME,FRANCISCO J. STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
description	Cross-linked copolymers of acrylamide (AAm) with N-[3-(dimethyl amine)propyl]methacrylamide (NDAPM) were prepared by solution free radical polymerization at different feed molar ratios. In this reaction, ammonium persulfate (APS) and N,N´-methylene-bis-acrylamide (MBA) were used as initiator and cross-linking reagents respectively. The effects of reaction parameters, including the concentration of crosslinking reagent and initiator, the monomer concentration, pH, temperature, the various salt solutions, and solvent polarity, on the water absorption have been investigated. The results indicate that the copolymers obtained are stimuli-responsive hydrogels that change their volume and elasticity in depending on the properties of the liquid phase
author	POOLEY,S. AMALIA RIVAS,BERNABÉ L. RIQUELME,FRANCISCO J.
author_facet	POOLEY,S. AMALIA RIVAS,BERNABÉ L. RIQUELME,FRANCISCO J.
author_sort	POOLEY,S. AMALIA
title	STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
title_short	STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
title_full	STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
title_fullStr	STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
title_full_unstemmed	STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES
title_sort	stimuli-responsive hydrogels from acrylamide with n-[3-(dimethylamine)propyl] metacrylamide: synthesis and properties
publisher	Sociedad Chilena de Química
publishDate	2007
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200009
work_keys_str_mv	AT pooleysamalia stimuliresponsivehydrogelsfromacrylamidewithn3dimethylaminepropylmetacrylamidesynthesisandproperties AT rivasbernabel stimuliresponsivehydrogelsfromacrylamidewithn3dimethylaminepropylmetacrylamidesynthesisandproperties AT riquelmefranciscoj stimuliresponsivehydrogelsfromacrylamidewithn3dimethylaminepropylmetacrylamidesynthesisandproperties
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STIMULI-RESPONSIVE HYDROGELS FROM ACRYLAMIDE WITH N-[3-(DIMETHYLAMINE)PROPYL] METACRYLAMIDE: SYNTHESIS AND PROPERTIES

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