REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES

The crosslinked resins poly(4-acryloylmorpholine-co-4-vinyl pyridine) P(AMo- VPy), poly(N-(3-dimethylamino)propylmethacrylamide-co-4-vinyl pyridine) P(NDAPA-VPy), and poly((3-dimethylamino)propylacrylate-co-4-vinyl pyridine) P(DAPA-VPy) were obtained by radical polymerization. The resins were comple...

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Autores principales:	RIVAS,BERNABÉ L, VILLEGAS,SANDRA, RUF,BEATRIZ, PERIC,IVÁN M
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2007
Materias:	resin radical polymerization metal ions polymer-metal complexes
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200010
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spelling	oai:scielo:S0717-970720070002000102007-09-13REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIESRIVAS,BERNABÉ LVILLEGAS,SANDRARUF,BEATRIZPERIC,IVÁN M resin radical polymerization metal ions polymer-metal complexes The crosslinked resins poly(4-acryloylmorpholine-co-4-vinyl pyridine) P(AMo- VPy), poly(N-(3-dimethylamino)propylmethacrylamide-co-4-vinyl pyridine) P(NDAPA-VPy), and poly((3-dimethylamino)propylacrylate-co-4-vinyl pyridine) P(DAPA-VPy) were obtained by radical polymerization. The resins were completely insoluble in water. The uptake metal ion properties are studied by batch equilibrium procedure for the following metal ions: silver(I), copper(II), cadmium(II), zinc(II), lead(II), mercury(II), chromium(III), and aluminum(III). P(AMo-VPy) resin shows a lower metal ion affinity than P(DAPA-VPy), except for Hg(II) which is retained in almost 100 % at pH 2. At pH 5, the resin shows the higher affinity for Ag(I) (80%) and Cu(II) (60%) but it is very low for Zn(II) and Cr(III). The polymer ligand metal ion equilibrium is achieved during the first 20 min. By changing the pH is possible to remove between 50 % and 70 % of Cd(II) and Cu(II) ions by using (1 M, 4 M) HClO4 and (1 M, 4 M) HNO3info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.2 20072007-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200010en10.4067/S0717-97072007000200010
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	resin radical polymerization metal ions polymer-metal complexes
spellingShingle	resin radical polymerization metal ions polymer-metal complexes RIVAS,BERNABÉ L VILLEGAS,SANDRA RUF,BEATRIZ PERIC,IVÁN M REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
description	The crosslinked resins poly(4-acryloylmorpholine-co-4-vinyl pyridine) P(AMo- VPy), poly(N-(3-dimethylamino)propylmethacrylamide-co-4-vinyl pyridine) P(NDAPA-VPy), and poly((3-dimethylamino)propylacrylate-co-4-vinyl pyridine) P(DAPA-VPy) were obtained by radical polymerization. The resins were completely insoluble in water. The uptake metal ion properties are studied by batch equilibrium procedure for the following metal ions: silver(I), copper(II), cadmium(II), zinc(II), lead(II), mercury(II), chromium(III), and aluminum(III). P(AMo-VPy) resin shows a lower metal ion affinity than P(DAPA-VPy), except for Hg(II) which is retained in almost 100 % at pH 2. At pH 5, the resin shows the higher affinity for Ag(I) (80%) and Cu(II) (60%) but it is very low for Zn(II) and Cr(III). The polymer ligand metal ion equilibrium is achieved during the first 20 min. By changing the pH is possible to remove between 50 % and 70 % of Cd(II) and Cu(II) ions by using (1 M, 4 M) HClO4 and (1 M, 4 M) HNO3
author	RIVAS,BERNABÉ L VILLEGAS,SANDRA RUF,BEATRIZ PERIC,IVÁN M
author_facet	RIVAS,BERNABÉ L VILLEGAS,SANDRA RUF,BEATRIZ PERIC,IVÁN M
author_sort	RIVAS,BERNABÉ L
title	REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
title_short	REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
title_full	REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
title_fullStr	REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
title_full_unstemmed	REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES
title_sort	removal of metal ions with impact on the environment by water-insoluble functional copolymers: synthesis and metal ion uptake properties
publisher	Sociedad Chilena de Química
publishDate	2007
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200010
work_keys_str_mv	AT rivasbernabel removalofmetalionswithimpactontheenvironmentbywaterinsolublefunctionalcopolymerssynthesisandmetalionuptakeproperties AT villegassandra removalofmetalionswithimpactontheenvironmentbywaterinsolublefunctionalcopolymerssynthesisandmetalionuptakeproperties AT rufbeatriz removalofmetalionswithimpactontheenvironmentbywaterinsolublefunctionalcopolymerssynthesisandmetalionuptakeproperties AT pericivanm removalofmetalionswithimpactontheenvironmentbywaterinsolublefunctionalcopolymerssynthesisandmetalionuptakeproperties
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REMOVAL OF METAL IONS WITH IMPACT ON THE ENVIRONMENT BY WATER-INSOLUBLE FUNCTIONAL COPOLYMERS: SYNTHESIS AND METAL ION UPTAKE PROPERTIES

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