STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N

The polymeric compounds formulated as [M(Biqui)(VO2)(PO4H2)(PO4H).(H2O)]n (Biqui=biquinoline ; M: Zn(II) (1); (Cu(II) 0.30Zn(II) 0.70, (2)) present [V2O2+2]n infinite chains to which two different M(Biqui)(PO4H2)(PO4H)-1 groups attach at both sides, to form broad, stable strips, H-bonded into a 2D s...

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Autores principales:	CÁRDENAS,G, BAGGIO,R, MORENO,Y, PEÑA,O, PIVAN,J-Y
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2007
Materias:	paramagnetism biquinoline copper hybrid compound
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200012
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spelling	oai:scielo:S0717-970720070002000122007-09-13STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·NCÁRDENAS,GBAGGIO,RMORENO,YPEÑA,OPIVAN,J-Y paramagnetism biquinoline copper hybrid compound The polymeric compounds formulated as [M(Biqui)(VO2)(PO4H2)(PO4H).(H2O)]n (Biqui=biquinoline ; M: Zn(II) (1); (Cu(II) 0.30Zn(II) 0.70, (2)) present [V2O2+2]n infinite chains to which two different M(Biqui)(PO4H2)(PO4H)-1 groups attach at both sides, to form broad, stable strips, H-bonded into a 2D structure parallel to (101). Stacking of planes is stabilized by π-π bonds between interdigitated Biqui groups. When M = Cu(II), magnetic interactions between metal centres are expected ; however, in the case presented herein (Cu/Zn = 0.3/0.7), magnetic dilution of paramagnetic copper prevents magnetic interactions to occurinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.2 20072007-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200012en10.4067/S0717-97072007000200012
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	paramagnetism biquinoline copper hybrid compound
spellingShingle	paramagnetism biquinoline copper hybrid compound CÁRDENAS,G BAGGIO,R MORENO,Y PEÑA,O PIVAN,J-Y STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
description	The polymeric compounds formulated as [M(Biqui)(VO2)(PO4H2)(PO4H).(H2O)]n (Biqui=biquinoline ; M: Zn(II) (1); (Cu(II) 0.30Zn(II) 0.70, (2)) present [V2O2+2]n infinite chains to which two different M(Biqui)(PO4H2)(PO4H)-1 groups attach at both sides, to form broad, stable strips, H-bonded into a 2D structure parallel to (101). Stacking of planes is stabilized by π-π bonds between interdigitated Biqui groups. When M = Cu(II), magnetic interactions between metal centres are expected ; however, in the case presented herein (Cu/Zn = 0.3/0.7), magnetic dilution of paramagnetic copper prevents magnetic interactions to occur
author	CÁRDENAS,G BAGGIO,R MORENO,Y PEÑA,O PIVAN,J-Y
author_facet	CÁRDENAS,G BAGGIO,R MORENO,Y PEÑA,O PIVAN,J-Y
author_sort	CÁRDENAS,G
title	STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
title_short	STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
title_full	STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
title_fullStr	STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
title_full_unstemmed	STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N
title_sort	structure and magnetic properties of an organic-inorganic hybrid compound: zn/cu (biquinoline)(vo2)(po4h2)(po4h).(h2o)]·n
publisher	Sociedad Chilena de Química
publishDate	2007
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000200012
work_keys_str_mv	AT cardenasg structureandmagneticpropertiesofanorganicinorganichybridcompoundzncubiquinolinevo2po4h2po4hh2on AT baggior structureandmagneticpropertiesofanorganicinorganichybridcompoundzncubiquinolinevo2po4h2po4hh2on AT morenoy structureandmagneticpropertiesofanorganicinorganichybridcompoundzncubiquinolinevo2po4h2po4hh2on AT penao structureandmagneticpropertiesofanorganicinorganichybridcompoundzncubiquinolinevo2po4h2po4hh2on AT pivanjy structureandmagneticpropertiesofanorganicinorganichybridcompoundzncubiquinolinevo2po4h2po4hh2on
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STRUCTURE AND MAGNETIC PROPERTIES OF AN ORGANIC-INORGANIC HYBRID COMPOUND: ZN/CU (BIQUINOLINE)(VO2)(PO4H2)(PO4H).(H2O)]·N

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