NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS

The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in...

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Autores principales:	BARTOLINP,M, MOLINA,J., ORTEGA,M. C, SOJO,P, PARDEY,A. J, LONGO,C., MOYA,S.A., FEAZELL,R. P
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2007
Materias:	Catalysis nitrobenzene reduction rhodium complexes carbon monoxide
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014
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spelling	oai:scielo:S0717-970720070003000142007-11-29NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDSBARTOLINP,MMOLINA,J.ORTEGA,M. CSOJO,PPARDEY,A. JLONGO,C.MOYA,S.A.FEAZELL,R. P Catalysis nitrobenzene reduction rhodium complexes carbon monoxide The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium centerinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.3 20072007-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014en10.4067/S0717-97072007000300014
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Catalysis nitrobenzene reduction rhodium complexes carbon monoxide
spellingShingle	Catalysis nitrobenzene reduction rhodium complexes carbon monoxide BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
description	The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium center
author	BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P
author_facet	BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P
author_sort	BARTOLINP,M
title	NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
title_short	NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
title_full	NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
title_fullStr	NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
title_full_unstemmed	NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
title_sort	nitrobenzene reduction catalized by soluble carbonylrhodium complexes of methyl and dimethyl pyridine ligands
publisher	Sociedad Chilena de Química
publishDate	2007
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014
work_keys_str_mv	AT bartolinpm nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT molinaj nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT ortegamc nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT sojop nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT pardeyaj nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT longoc nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT moyasa nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT feazellrp nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands
_version_	1718445376517701632

NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS

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