NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS

The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in...

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Autores principales: BARTOLINP,M, MOLINA,J., ORTEGA,M. C, SOJO,P, PARDEY,A. J, LONGO,C., MOYA,S.A., FEAZELL,R. P
Lenguaje:English
Publicado: Sociedad Chilena de Química 2007
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014
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