SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE

Sisyl radicals generated from frá(trimethylsilyl)silane were reacted with allyloxy benzaldehydes and the sequential radical process of was studied. After desisylation, the corresponding chromanols were successfully obtained

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Autores principales: JARAMILLO-GÓMEZ,LUZ MARINA, MARTIN,JAIME, RÍOS,LUZ AMALIA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2007
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000400001
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spelling oai:scielo:S0717-970720070004000012008-04-30SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANEJARAMILLO-GÓMEZ,LUZ MARINAMARTIN,JAIMERÍOS,LUZ AMALIA O-sisyl ketyl radicals radical addition cyclization allyloxybenzaldehydes chromanols sisyl ether tris(trimethylsilyl)silane Sisyl radicals generated from frá(trimethylsilyl)silane were reacted with allyloxy benzaldehydes and the sequential radical process of was studied. After desisylation, the corresponding chromanols were successfully obtainedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.4 20072007-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000400001en10.4067/S0717-97072007000400001
institution Scielo Chile
collection Scielo Chile
language English
topic O-sisyl ketyl radicals
radical addition
cyclization
allyloxybenzaldehydes
chromanols
sisyl ether
tris(trimethylsilyl)silane
spellingShingle O-sisyl ketyl radicals
radical addition
cyclization
allyloxybenzaldehydes
chromanols
sisyl ether
tris(trimethylsilyl)silane
JARAMILLO-GÓMEZ,LUZ MARINA
MARTIN,JAIME
RÍOS,LUZ AMALIA
SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
description Sisyl radicals generated from frá(trimethylsilyl)silane were reacted with allyloxy benzaldehydes and the sequential radical process of was studied. After desisylation, the corresponding chromanols were successfully obtained
author JARAMILLO-GÓMEZ,LUZ MARINA
MARTIN,JAIME
RÍOS,LUZ AMALIA
author_facet JARAMILLO-GÓMEZ,LUZ MARINA
MARTIN,JAIME
RÍOS,LUZ AMALIA
author_sort JARAMILLO-GÓMEZ,LUZ MARINA
title SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
title_short SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
title_full SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
title_fullStr SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
title_full_unstemmed SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
title_sort synthesis of chromanols by tandem radical addition/cyclization mediated by tris(tri methylsilyl)silane
publisher Sociedad Chilena de Química
publishDate 2007
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000400001
work_keys_str_mv AT jaramillogomezluzmarina synthesisofchromanolsbytandemradicaladditioncyclizationmediatedbytristrimethylsilylsilane
AT martinjaime synthesisofchromanolsbytandemradicaladditioncyclizationmediatedbytristrimethylsilylsilane
AT riosluzamalia synthesisofchromanolsbytandemradicaladditioncyclizationmediatedbytristrimethylsilylsilane
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