A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES

A new ionic organic-inorganic hybrid complex of formula («-Bu4N)2[Mo(¡0(18)(NR)]¹/2Me2CO, R = -C6H2-2,6-Me2-4-Br, (w-Bu4N)2[l]-i4Me2CO, has been prepared in acetonitrile by reacting tetrabutylammonium a-octamolybdate, («-Bu4N)4[0t-Mo8O26], with 2,6-dimethyl-4-bromoaniline hydrochloride, 2,6-Me2-4-Br...

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Autores principales:	CORTÉS,MARCELA, FUENTEALBA,MAURICIO, MANZUR,CAROLINA, CARRILLO,DAVID
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2008
Materias:	areneimido-derivative phenylimido-derivative Lindqvist-type hexamolybdate polyoxometalate crystal structure conformational isomers
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100004
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spelling	oai:scielo:S0717-970720080001000042008-07-03A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIESCORTÉS,MARCELAFUENTEALBA,MAURICIOMANZUR,CAROLINACARRILLO,DAVID areneimido-derivative phenylimido-derivative Lindqvist-type hexamolybdate polyoxometalate crystal structure conformational isomers A new ionic organic-inorganic hybrid complex of formula («-Bu4N)2[Mo(¡0(18)(NR)]¹/2Me2CO, R = -C6H2-2,6-Me2-4-Br, (w-Bu4N)2[l]-i4Me2CO, has been prepared in acetonitrile by reacting tetrabutylammonium a-octamolybdate, («-Bu4N)4[0t-Mo8O26], with 2,6-dimethyl-4-bromoaniline hydrochloride, 2,6-Me2-4-Br-C6H2NH2HCl, using N,N'-dicyclohexylcarbodiimide, (C6H U)N=C=N(C6H11), as dehydrating agent. This complex, formulated as («-Bu4N)2[l]¹/2Me2CO, contains a C-Br group which can be functionahzed for constructing novel hybrid materials. The complex was fully characterized by IR, UV-Vis, 'H- and "C-NMR spectroscopies, and authenticated by single crystal X-ray diffraction analysis. The asymmetric unit contains two crystallographically independent anions, [l]²", differing by the orientation of the phenyl ring relative to the hexamolybdate skeleton, and one molecule of acetone. Both molecules differ in the angles Mo(l)-N(l)-C(l)= 172.2(6) and Mo(7)-N(2)-C(9)= 175.6(6)°. These angles, near to 180°, indicate the presence of a Mo=N triple bondinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100004en10.4067/S0717-97072008000100004
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	areneimido-derivative phenylimido-derivative Lindqvist-type hexamolybdate polyoxometalate crystal structure conformational isomers
spellingShingle	areneimido-derivative phenylimido-derivative Lindqvist-type hexamolybdate polyoxometalate crystal structure conformational isomers CORTÉS,MARCELA FUENTEALBA,MAURICIO MANZUR,CAROLINA CARRILLO,DAVID A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
description	A new ionic organic-inorganic hybrid complex of formula («-Bu4N)2[Mo(¡0(18)(NR)]¹/2Me2CO, R = -C6H2-2,6-Me2-4-Br, (w-Bu4N)2[l]-i4Me2CO, has been prepared in acetonitrile by reacting tetrabutylammonium a-octamolybdate, («-Bu4N)4[0t-Mo8O26], with 2,6-dimethyl-4-bromoaniline hydrochloride, 2,6-Me2-4-Br-C6H2NH2HCl, using N,N'-dicyclohexylcarbodiimide, (C6H U)N=C=N(C6H11), as dehydrating agent. This complex, formulated as («-Bu4N)2[l]¹/2Me2CO, contains a C-Br group which can be functionahzed for constructing novel hybrid materials. The complex was fully characterized by IR, UV-Vis, 'H- and "C-NMR spectroscopies, and authenticated by single crystal X-ray diffraction analysis. The asymmetric unit contains two crystallographically independent anions, [l]²", differing by the orientation of the phenyl ring relative to the hexamolybdate skeleton, and one molecule of acetone. Both molecules differ in the angles Mo(l)-N(l)-C(l)= 172.2(6) and Mo(7)-N(2)-C(9)= 175.6(6)°. These angles, near to 180°, indicate the presence of a Mo=N triple bond
author	CORTÉS,MARCELA FUENTEALBA,MAURICIO MANZUR,CAROLINA CARRILLO,DAVID
author_facet	CORTÉS,MARCELA FUENTEALBA,MAURICIO MANZUR,CAROLINA CARRILLO,DAVID
author_sort	CORTÉS,MARCELA
title	A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
title_short	A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
title_full	A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
title_fullStr	A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
title_full_unstemmed	A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES
title_sort	new lindqvist-type hexamolybdate cluster functionalized with the jt-donor ligand 4-bromo-2,6-dimethylphenylimido: spectroscopic, electrochemical and structural studies
publisher	Sociedad Chilena de Química
publishDate	2008
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100004
work_keys_str_mv	AT cortesmarcela anewlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT fuentealbamauricio anewlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT manzurcarolina anewlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT carrillodavid anewlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT cortesmarcela newlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT fuentealbamauricio newlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT manzurcarolina newlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies AT carrillodavid newlindqvisttypehexamolybdateclusterfunctionalizedwiththejtdonorligand4bromo26dimethylphenylimidospectroscopicelectrochemicalandstructuralstudies
_version_	1718445380943740928

A NEW LINDQVIST-TYPE HEXAMOLYBDATE CLUSTER FUNCTIONALIZED WITH THE jt-DONOR LIGAND 4-BROMO-2,6-DIMETHYLPHENYLIMIDO: SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES

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