CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0

Monoaquatris(tetraoxorhenate (VII)) bismuth(III), Bi(Re0(4))3(H(2)0) was prepared by reaction of (BiO)2C0(3)/Bi2(C0(3))3 with concentrated HRe0(4) at room temperature. The pale yellow compound crystallize triclinic in the space group PI;, (No. 2); with two formula units per unit cell (a = 746.0(1) p...

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Autores principales:	MUJICA,CARLOS, LLANOS,JAIME, SÁNCHEZ,VÍCTOR, BOCAZ,PAOLA, CARDOSO-GIL,RAÚL
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2008
Materias:	crystal structure perrhenate anions X-ray diffraction coordination number
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100008
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spelling	oai:scielo:S0717-970720080001000082008-07-03CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0MUJICA,CARLOSLLANOS,JAIMESÁNCHEZ,VÍCTORBOCAZ,PAOLACARDOSO-GIL,RAÚL crystal structure perrhenate anions X-ray diffraction coordination number Monoaquatris(tetraoxorhenate (VII)) bismuth(III), Bi(Re0(4))3(H(2)0) was prepared by reaction of (BiO)2C0(3)/Bi2(C0(3))3 with concentrated HRe0(4) at room temperature. The pale yellow compound crystallize triclinic in the space group PI;, (No. 2); with two formula units per unit cell (a = 746.0(1) pm, b = 111. 1(2) pm, c = 990.5(2) pm, a = 100.99(3)°, p = 99.88(3)°, y = 100.17(3)° ). The main feature of the crystal structure is a distorted bicapped trigonal prism of Bi[(Re0(4))3;2 (Re0(4))2/2 (Re0(4))2/2 (H(2)0)], which are connected each other through [ReOJ-tetrahedra to form a three-dimensional network. In the titled compound, the cation Bi3+ is eightfold coordinated which agree with the tendency observed in other compounds of the familyinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100008en10.4067/S0717-97072008000100008
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	crystal structure perrhenate anions X-ray diffraction coordination number
spellingShingle	crystal structure perrhenate anions X-ray diffraction coordination number MUJICA,CARLOS LLANOS,JAIME SÁNCHEZ,VÍCTOR BOCAZ,PAOLA CARDOSO-GIL,RAÚL CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
description	Monoaquatris(tetraoxorhenate (VII)) bismuth(III), Bi(Re0(4))3(H(2)0) was prepared by reaction of (BiO)2C0(3)/Bi2(C0(3))3 with concentrated HRe0(4) at room temperature. The pale yellow compound crystallize triclinic in the space group PI;, (No. 2); with two formula units per unit cell (a = 746.0(1) pm, b = 111. 1(2) pm, c = 990.5(2) pm, a = 100.99(3)°, p = 99.88(3)°, y = 100.17(3)° ). The main feature of the crystal structure is a distorted bicapped trigonal prism of Bi[(Re0(4))3;2 (Re0(4))2/2 (Re0(4))2/2 (H(2)0)], which are connected each other through [ReOJ-tetrahedra to form a three-dimensional network. In the titled compound, the cation Bi3+ is eightfold coordinated which agree with the tendency observed in other compounds of the family
author	MUJICA,CARLOS LLANOS,JAIME SÁNCHEZ,VÍCTOR BOCAZ,PAOLA CARDOSO-GIL,RAÚL
author_facet	MUJICA,CARLOS LLANOS,JAIME SÁNCHEZ,VÍCTOR BOCAZ,PAOLA CARDOSO-GIL,RAÚL
author_sort	MUJICA,CARLOS
title	CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
title_short	CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
title_full	CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
title_fullStr	CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
title_full_unstemmed	CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0
title_sort	crystal structure of a new bismuth perrhenate bi(re0(4))3h(2)0
publisher	Sociedad Chilena de Química
publishDate	2008
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100008
work_keys_str_mv	AT mujicacarlos crystalstructureofanewbismuthperrhenatebire043h20 AT llanosjaime crystalstructureofanewbismuthperrhenatebire043h20 AT sanchezvictor crystalstructureofanewbismuthperrhenatebire043h20 AT bocazpaola crystalstructureofanewbismuthperrhenatebire043h20 AT cardosogilraul crystalstructureofanewbismuthperrhenatebire043h20
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CRYSTAL STRUCTURE OF A NEW BISMUTH PERRHENATE Bi(Re0(4))3H(2)0

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