THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS

A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex

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Autores principales: PARADA,JOSÉ, LARRAZÁBAL,GUILLERMO, AGUIRRE,PEDRO, ZOLEZZI,SANTIAGO, VEGA,CARMEN, GARRIDO,CRISTIAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100012
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Sumario:A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex