THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS

A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex

Guardado en:
Detalles Bibliográficos
Autores principales: PARADA,JOSÉ, LARRAZÁBAL,GUILLERMO, AGUIRRE,PEDRO, ZOLEZZI,SANTIAGO, VEGA,CARMEN, GARRIDO,CRISTIAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
Materias:
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100012
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:scielo:S0717-97072008000100012
record_format dspace
spelling oai:scielo:S0717-970720080001000122008-07-03THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARSPARADA,JOSÉLARRAZÁBAL,GUILLERMOAGUIRRE,PEDROZOLEZZI,SANTIAGOVEGA,CARMENGARRIDO,CRISTIAN Werner complex hexol sugar Co(III) circular dichroism dd* transition dd* enantioselectivity A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complexinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100012en10.4067/S0717-97072008000100012
institution Scielo Chile
collection Scielo Chile
language English
topic Werner complex
hexol
sugar
Co(III)
circular dichroism
dd* transition dd*
enantioselectivity
spellingShingle Werner complex
hexol
sugar
Co(III)
circular dichroism
dd* transition dd*
enantioselectivity
PARADA,JOSÉ
LARRAZÁBAL,GUILLERMO
AGUIRRE,PEDRO
ZOLEZZI,SANTIAGO
VEGA,CARMEN
GARRIDO,CRISTIAN
THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
description A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex
author PARADA,JOSÉ
LARRAZÁBAL,GUILLERMO
AGUIRRE,PEDRO
ZOLEZZI,SANTIAGO
VEGA,CARMEN
GARRIDO,CRISTIAN
author_facet PARADA,JOSÉ
LARRAZÁBAL,GUILLERMO
AGUIRRE,PEDRO
ZOLEZZI,SANTIAGO
VEGA,CARMEN
GARRIDO,CRISTIAN
author_sort PARADA,JOSÉ
title THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
title_short THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
title_full THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
title_fullStr THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
title_full_unstemmed THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS
title_sort stereoselective synthesis of the werner complex with substoichiometric sugars
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100012
work_keys_str_mv AT paradajose thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT larrazabalguillermo thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT aguirrepedro thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT zolezzisantiago thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT vegacarmen thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT garridocristian thestereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT paradajose stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT larrazabalguillermo stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT aguirrepedro stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT zolezzisantiago stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT vegacarmen stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
AT garridocristian stereoselectivesynthesisofthewernercomplexwithsubstoichiometricsugars
_version_ 1718445382449496064