A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicab...
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Sociedad Chilena de Química
2008
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oai:scielo:S0717-970720080001000152008-07-03A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONSLAM,ELIZABETH JALVAREZ,MIGUEL N.GALVEZ,MARÍA E.ALVAREZ,EDUARDO B. Density multicomponent systems aqueous solutions electrolytes A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicable to simple 1:1 aqueous electrolyte solutions which in the present study was extended to multicomponent systems and for any type of salt. Seventeen aqueous systems containing 2, 3, and 4 salts were studied, obtaining excellent results when compared with the experimental values. The total relative mean standard deviation obtained was 0.08 %. The proposed method used adjustable parameters, which are obtained beginning from experimental data from systems containing a single salt. Two parameters are required for each ion present in the aqueous solutioninfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100015en10.4067/S0717-97072008000100015 |
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Scielo Chile |
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Scielo Chile |
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English |
topic |
Density multicomponent systems aqueous solutions electrolytes |
spellingShingle |
Density multicomponent systems aqueous solutions electrolytes LAM,ELIZABETH J ALVAREZ,MIGUEL N. GALVEZ,MARÍA E. ALVAREZ,EDUARDO B. A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
description |
A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicable to simple 1:1 aqueous electrolyte solutions which in the present study was extended to multicomponent systems and for any type of salt. Seventeen aqueous systems containing 2, 3, and 4 salts were studied, obtaining excellent results when compared with the experimental values. The total relative mean standard deviation obtained was 0.08 %. The proposed method used adjustable parameters, which are obtained beginning from experimental data from systems containing a single salt. Two parameters are required for each ion present in the aqueous solution |
author |
LAM,ELIZABETH J ALVAREZ,MIGUEL N. GALVEZ,MARÍA E. ALVAREZ,EDUARDO B. |
author_facet |
LAM,ELIZABETH J ALVAREZ,MIGUEL N. GALVEZ,MARÍA E. ALVAREZ,EDUARDO B. |
author_sort |
LAM,ELIZABETH J |
title |
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
title_short |
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
title_full |
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
title_fullStr |
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
title_full_unstemmed |
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS |
title_sort |
model for calculating the density of aqueous multicomponent electrolyte solutions |
publisher |
Sociedad Chilena de Química |
publishDate |
2008 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100015 |
work_keys_str_mv |
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