A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS

A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicab...

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Autores principales: LAM,ELIZABETH J, ALVAREZ,MIGUEL N., GALVEZ,MARÍA E., ALVAREZ,EDUARDO B.
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100015
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spelling oai:scielo:S0717-970720080001000152008-07-03A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONSLAM,ELIZABETH JALVAREZ,MIGUEL N.GALVEZ,MARÍA E.ALVAREZ,EDUARDO B. Density multicomponent systems aqueous solutions electrolytes A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicable to simple 1:1 aqueous electrolyte solutions which in the present study was extended to multicomponent systems and for any type of salt. Seventeen aqueous systems containing 2, 3, and 4 salts were studied, obtaining excellent results when compared with the experimental values. The total relative mean standard deviation obtained was 0.08 %. The proposed method used adjustable parameters, which are obtained beginning from experimental data from systems containing a single salt. Two parameters are required for each ion present in the aqueous solutioninfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100015en10.4067/S0717-97072008000100015
institution Scielo Chile
collection Scielo Chile
language English
topic Density
multicomponent systems
aqueous solutions
electrolytes
spellingShingle Density
multicomponent systems
aqueous solutions
electrolytes
LAM,ELIZABETH J
ALVAREZ,MIGUEL N.
GALVEZ,MARÍA E.
ALVAREZ,EDUARDO B.
A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
description A method is presented for calculating the densities of simple and multicomponent aqueous saline solutions. A total of 38 parameters were obtained for anions and cations which allowed predicting their density in aqueous solution. The proposed method is based on the model of Hórsak and Slama¹ applicable to simple 1:1 aqueous electrolyte solutions which in the present study was extended to multicomponent systems and for any type of salt. Seventeen aqueous systems containing 2, 3, and 4 salts were studied, obtaining excellent results when compared with the experimental values. The total relative mean standard deviation obtained was 0.08 %. The proposed method used adjustable parameters, which are obtained beginning from experimental data from systems containing a single salt. Two parameters are required for each ion present in the aqueous solution
author LAM,ELIZABETH J
ALVAREZ,MIGUEL N.
GALVEZ,MARÍA E.
ALVAREZ,EDUARDO B.
author_facet LAM,ELIZABETH J
ALVAREZ,MIGUEL N.
GALVEZ,MARÍA E.
ALVAREZ,EDUARDO B.
author_sort LAM,ELIZABETH J
title A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
title_short A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
title_full A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
title_fullStr A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
title_full_unstemmed A MODEL FOR CALCULATING THE DENSITY OF AQUEOUS MULTICOMPONENT ELECTROLYTE SOLUTIONS
title_sort model for calculating the density of aqueous multicomponent electrolyte solutions
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100015
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