STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL

A study was made on the effect of temperature on the electrodeposition of hard chromium on 1045 steel within a range of 30° to 60°C, as shown by variations in reaction yield, surface hardness, and depositional grain size. Increase in temperature produced a decrease in faradic yield of the reaction o...

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Autores principales: BARBATO R,SALVADOR, PONCE F,JILBERTO, JARA V,MARCELO, CUEVAS S,JACQUELINE, EGAÑA A,RODRIGO
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100022
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spelling oai:scielo:S0717-970720080001000222008-07-03STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEELBARBATO R,SALVADORPONCE F,JILBERTOJARA V,MARCELOCUEVAS S,JACQUELINEEGAÑA A,RODRIGO electroplating hard chromium hardness grain size reaction yield chrono potentiometric and potentiodinamic linear sweep A study was made on the effect of temperature on the electrodeposition of hard chromium on 1045 steel within a range of 30° to 60°C, as shown by variations in reaction yield, surface hardness, and depositional grain size. Increase in temperature produced a decrease in faradic yield of the reaction of between 17% and 9%, an increase in hardness from 550 to 700 Brinelli, and a decrease in deposited chromium grain size from 278 to 32.4 urn. The most notable effect of temperature difference was observed between 30° and 40°C. Chrono-potentiometric and potentiodinamic linear sweep were measured at 30°C, 40°C and 50 °C in an attempt to explain this behavior. The results obtained suggested the formation of a compact film typical of a nucleation process in chromium electrodeposition. An increase in temperature affects the formation of this film, decreasing its thickness and distributing it in a more homogeneous manner over the steel, as shown by a decrease in the grain size of the chrome depositedinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.1 20082008-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100022en10.4067/S0717-97072008000100022
institution Scielo Chile
collection Scielo Chile
language English
topic electroplating
hard chromium
hardness
grain size
reaction yield chrono potentiometric and potentiodinamic linear sweep
spellingShingle electroplating
hard chromium
hardness
grain size
reaction yield chrono potentiometric and potentiodinamic linear sweep
BARBATO R,SALVADOR
PONCE F,JILBERTO
JARA V,MARCELO
CUEVAS S,JACQUELINE
EGAÑA A,RODRIGO
STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
description A study was made on the effect of temperature on the electrodeposition of hard chromium on 1045 steel within a range of 30° to 60°C, as shown by variations in reaction yield, surface hardness, and depositional grain size. Increase in temperature produced a decrease in faradic yield of the reaction of between 17% and 9%, an increase in hardness from 550 to 700 Brinelli, and a decrease in deposited chromium grain size from 278 to 32.4 urn. The most notable effect of temperature difference was observed between 30° and 40°C. Chrono-potentiometric and potentiodinamic linear sweep were measured at 30°C, 40°C and 50 °C in an attempt to explain this behavior. The results obtained suggested the formation of a compact film typical of a nucleation process in chromium electrodeposition. An increase in temperature affects the formation of this film, decreasing its thickness and distributing it in a more homogeneous manner over the steel, as shown by a decrease in the grain size of the chrome deposited
author BARBATO R,SALVADOR
PONCE F,JILBERTO
JARA V,MARCELO
CUEVAS S,JACQUELINE
EGAÑA A,RODRIGO
author_facet BARBATO R,SALVADOR
PONCE F,JILBERTO
JARA V,MARCELO
CUEVAS S,JACQUELINE
EGAÑA A,RODRIGO
author_sort BARBATO R,SALVADOR
title STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
title_short STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
title_full STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
title_fullStr STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
title_full_unstemmed STUDY OF THE EFFECT OF TEMPERATURE ON THE HARDNESS, GRAIN SIZE, AND YIELD IN ELECTRODEPOSITION OF CHROMIUM ON 1045 STEEL
title_sort study of the effect of temperature on the hardness, grain size, and yield in electrodeposition of chromium on 1045 steel
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000100022
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