INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB

The intercalation compounds Li0,43(PEO)2.4(H2O)1.4K0.57BiP2S6 and Li0.38(PEO)2.1(H2O)1.6K0.62SbP2S6 have been synthesized by the insertion of polyethylene oxide PEO in LiKMP2S6 (M=Bi, Sb), that contained Li+ and K+ exchangeable cations in their interlayer space. The polymer PEO is able to associate...

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Autores principales:	RUIZ LEÓN,DOMINGO, GALDÁMEZ,ANTONIO, MANRÍQUEZ,VÍCTOR
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2008
Materias:	Intercalation Chalcogenides Layered compound
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200006
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id	oai:scielo:S0717-97072008000200006
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spelling	oai:scielo:S0717-970720080002000062009-06-09INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SBRUIZ LEÓN,DOMINGOGALDÁMEZ,ANTONIOMANRÍQUEZ,VÍCTOR Intercalation Chalcogenides Layered compound The intercalation compounds Li0,43(PEO)2.4(H2O)1.4K0.57BiP2S6 and Li0.38(PEO)2.1(H2O)1.6K0.62SbP2S6 have been synthesized by the insertion of polyethylene oxide PEO in LiKMP2S6 (M=Bi, Sb), that contained Li+ and K+ exchangeable cations in their interlayer space. The polymer PEO is able to associate interlayer Li+ cation modifying the ionic conductivity of pristine phases. These intercalation compounds constitute a new family of intercalates in the thiophosphate of Bi and Sb with Polyethylene oxide as guest species. They have been characterized by powder X-ray diffraction, FTIR-Raman, DTA/TGA analysis and electrical conductivity measurements. The studied nanocomposite shows values of electrical conductivity (σi) of about 10-6 Ω-1 cm-1 at room temperature.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.2 20082008-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200006en10.4067/S0717-97072008000200006
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Intercalation Chalcogenides Layered compound
spellingShingle	Intercalation Chalcogenides Layered compound RUIZ LEÓN,DOMINGO GALDÁMEZ,ANTONIO MANRÍQUEZ,VÍCTOR INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
description	The intercalation compounds Li0,43(PEO)2.4(H2O)1.4K0.57BiP2S6 and Li0.38(PEO)2.1(H2O)1.6K0.62SbP2S6 have been synthesized by the insertion of polyethylene oxide PEO in LiKMP2S6 (M=Bi, Sb), that contained Li+ and K+ exchangeable cations in their interlayer space. The polymer PEO is able to associate interlayer Li+ cation modifying the ionic conductivity of pristine phases. These intercalation compounds constitute a new family of intercalates in the thiophosphate of Bi and Sb with Polyethylene oxide as guest species. They have been characterized by powder X-ray diffraction, FTIR-Raman, DTA/TGA analysis and electrical conductivity measurements. The studied nanocomposite shows values of electrical conductivity (σi) of about 10-6 Ω-1 cm-1 at room temperature.
author	RUIZ LEÓN,DOMINGO GALDÁMEZ,ANTONIO MANRÍQUEZ,VÍCTOR
author_facet	RUIZ LEÓN,DOMINGO GALDÁMEZ,ANTONIO MANRÍQUEZ,VÍCTOR
author_sort	RUIZ LEÓN,DOMINGO
title	INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
title_short	INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
title_full	INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
title_fullStr	INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
title_full_unstemmed	INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB
title_sort	intercalation of polyethylene oxide in layered thiophosphate of bi and sb
publisher	Sociedad Chilena de Química
publishDate	2008
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200006
work_keys_str_mv	AT ruizleondomingo intercalationofpolyethyleneoxideinlayeredthiophosphateofbiandsb AT galdamezantonio intercalationofpolyethyleneoxideinlayeredthiophosphateofbiandsb AT manriquezvictor intercalationofpolyethyleneoxideinlayeredthiophosphateofbiandsb
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INTERCALATION OF POLYETHYLENE OXIDE IN LAYERED THIOPHOSPHATE OF BI AND SB

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