SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)

Reaction of the dinuclear complex [{Ru(CO)3Cl2}J with the Hgand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k²-PyPOPh2-N,0)(CO)2Cl2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structur...

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Autores principales: DÍAZ,OSCAR, MEDINA,SOLEDAD, VALDERRAMA,MAURICIO, LAHOZ,FERNANDO J, MARTÍN,M. LUISA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200007
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spelling oai:scielo:S0717-970720080002000072009-06-09SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)DÍAZ,OSCARMEDINA,SOLEDADVALDERRAMA,MAURICIOLAHOZ,FERNANDO JMARTÍN,M. LUISA Ruthenium 2-(diphenylphosphineoxide)pyridine complexes Dicarbonyl complexes Crystal structure Reaction of the dinuclear complex [{Ru(CO)3Cl2}J with the Hgand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k²-PyPOPh2-N,0)(CO)2Cl2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structure was determined by single-crystal X-ray diffraction.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.2 20082008-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200007en10.4067/S0717-97072008000200007
institution Scielo Chile
collection Scielo Chile
language English
topic Ruthenium
2-(diphenylphosphineoxide)pyridine complexes
Dicarbonyl complexes
Crystal structure
spellingShingle Ruthenium
2-(diphenylphosphineoxide)pyridine complexes
Dicarbonyl complexes
Crystal structure
DÍAZ,OSCAR
MEDINA,SOLEDAD
VALDERRAMA,MAURICIO
LAHOZ,FERNANDO J
MARTÍN,M. LUISA
SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
description Reaction of the dinuclear complex [{Ru(CO)3Cl2}J with the Hgand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k²-PyPOPh2-N,0)(CO)2Cl2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structure was determined by single-crystal X-ray diffraction.
author DÍAZ,OSCAR
MEDINA,SOLEDAD
VALDERRAMA,MAURICIO
LAHOZ,FERNANDO J
MARTÍN,M. LUISA
author_facet DÍAZ,OSCAR
MEDINA,SOLEDAD
VALDERRAMA,MAURICIO
LAHOZ,FERNANDO J
MARTÍN,M. LUISA
author_sort DÍAZ,OSCAR
title SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
title_short SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
title_full SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
title_fullStr SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
title_full_unstemmed SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)
title_sort synthesis and structure of dicarbonyldichloro{2-(diphenylphosphineoxide)pyridine}ruthenium(ii)
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200007
work_keys_str_mv AT diazoscar synthesisandstructureofdicarbonyldichloro2diphenylphosphineoxidepyridinerutheniumii
AT medinasoledad synthesisandstructureofdicarbonyldichloro2diphenylphosphineoxidepyridinerutheniumii
AT valderramamauricio synthesisandstructureofdicarbonyldichloro2diphenylphosphineoxidepyridinerutheniumii
AT lahozfernandoj synthesisandstructureofdicarbonyldichloro2diphenylphosphineoxidepyridinerutheniumii
AT martinmluisa synthesisandstructureofdicarbonyldichloro2diphenylphosphineoxidepyridinerutheniumii
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