LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY

Lithium cobaltite, LiCo(2)0(4), prepared by thermal decomposition of nitrates salts was synthesized at 400 °C. X-ray Rietveld refinement showed the presence of two phases: a cubic spinel (Co(3)0(4)) and other corresponding to spinel-like, which could not be classified as LiCo(2)0(4) or LiCo0(2) sinc...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: MEZA,ERIKA, ALBURQUENQUE,DANIELA, ORTIZ,JUAN, GAUTIER,JUAN LUIS
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
Materias:
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200010
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:scielo:S0717-97072008000200010
record_format dspace
spelling oai:scielo:S0717-970720080002000102009-06-09LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDYMEZA,ERIKAALBURQUENQUE,DANIELAORTIZ,JUANGAUTIER,JUAN LUIS lithium cobalt oxide lithium intercalation materials lithium ion batteries spinel mixed oxides Lithium cobaltite, LiCo(2)0(4), prepared by thermal decomposition of nitrates salts was synthesized at 400 °C. X-ray Rietveld refinement showed the presence of two phases: a cubic spinel (Co(3)0(4)) and other corresponding to spinel-like, which could not be classified as LiCo(2)0(4) or LiCo0(2) since both crystallized in Fd3m S.G. Electrochemical determinations (charge-discharge curves and impedance spectroscopy measurements) showed that Li+ ion is inserted into the spinel lattice, with D = 8 10-16 cm s-1 at 2.00-2.25 V potential range whereas lithium extraction occurred at 3.2-3.8 V potential range.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.2 20082008-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200010en10.4067/S0717-97072008000200010
institution Scielo Chile
collection Scielo Chile
language English
topic lithium cobalt oxide
lithium intercalation materials
lithium ion batteries
spinel
mixed oxides
spellingShingle lithium cobalt oxide
lithium intercalation materials
lithium ion batteries
spinel
mixed oxides
MEZA,ERIKA
ALBURQUENQUE,DANIELA
ORTIZ,JUAN
GAUTIER,JUAN LUIS
LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
description Lithium cobaltite, LiCo(2)0(4), prepared by thermal decomposition of nitrates salts was synthesized at 400 °C. X-ray Rietveld refinement showed the presence of two phases: a cubic spinel (Co(3)0(4)) and other corresponding to spinel-like, which could not be classified as LiCo(2)0(4) or LiCo0(2) since both crystallized in Fd3m S.G. Electrochemical determinations (charge-discharge curves and impedance spectroscopy measurements) showed that Li+ ion is inserted into the spinel lattice, with D = 8 10-16 cm s-1 at 2.00-2.25 V potential range whereas lithium extraction occurred at 3.2-3.8 V potential range.
author MEZA,ERIKA
ALBURQUENQUE,DANIELA
ORTIZ,JUAN
GAUTIER,JUAN LUIS
author_facet MEZA,ERIKA
ALBURQUENQUE,DANIELA
ORTIZ,JUAN
GAUTIER,JUAN LUIS
author_sort MEZA,ERIKA
title LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
title_short LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
title_full LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
title_fullStr LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
title_full_unstemmed LITHIUM COBALT SPINEL OXIDE: A STRUCTURAL AND ELECTROCHEMICAL STUDY
title_sort lithium cobalt spinel oxide: a structural and electrochemical study
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200010
work_keys_str_mv AT mezaerika lithiumcobaltspineloxideastructuralandelectrochemicalstudy
AT alburquenquedaniela lithiumcobaltspineloxideastructuralandelectrochemicalstudy
AT ortizjuan lithiumcobaltspineloxideastructuralandelectrochemicalstudy
AT gautierjuanluis lithiumcobaltspineloxideastructuralandelectrochemicalstudy
_version_ 1718445386851418112