p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE

p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt...

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Autores principales: CHORDIA,LEENA, CHATURVEDI,ALOK
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002
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spelling oai:scielo:S0717-970720080004000022009-05-22p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATECHORDIA,LEENACHATURVEDI,ALOK - p-Bromo nitrobenzene p-nitrobenzoyl chloride ammonium salt of alkylene dithiophosphoric acids p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ('H and 31P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.4 20082008-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002en10.4067/S0717-97072008000400002
institution Scielo Chile
collection Scielo Chile
language English
topic - p-Bromo nitrobenzene
p-nitrobenzoyl chloride
ammonium salt of alkylene dithiophosphoric acids
spellingShingle - p-Bromo nitrobenzene
p-nitrobenzoyl chloride
ammonium salt of alkylene dithiophosphoric acids
CHORDIA,LEENA
CHATURVEDI,ALOK
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
description p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ('H and 31P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature.
author CHORDIA,LEENA
CHATURVEDI,ALOK
author_facet CHORDIA,LEENA
CHATURVEDI,ALOK
author_sort CHORDIA,LEENA
title p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
title_short p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
title_full p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
title_fullStr p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
title_full_unstemmed p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
title_sort p-nitrophenyl and p-nitrobenzoyl derivatives of 0,0' - alkylene dithiophosphate
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002
work_keys_str_mv AT chordialeena pnitrophenylandpnitrobenzoylderivativesof00alkylenedithiophosphate
AT chaturvedialok pnitrophenylandpnitrobenzoylderivativesof00alkylenedithiophosphate
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