p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt...
Guardado en:
Autores principales: | , |
---|---|
Lenguaje: | English |
Publicado: |
Sociedad Chilena de Química
2008
|
Materias: | |
Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:scielo:S0717-97072008000400002 |
---|---|
record_format |
dspace |
spelling |
oai:scielo:S0717-970720080004000022009-05-22p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATECHORDIA,LEENACHATURVEDI,ALOK - p-Bromo nitrobenzene p-nitrobenzoyl chloride ammonium salt of alkylene dithiophosphoric acids p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ('H and 31P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.4 20082008-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002en10.4067/S0717-97072008000400002 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
- p-Bromo nitrobenzene p-nitrobenzoyl chloride ammonium salt of alkylene dithiophosphoric acids |
spellingShingle |
- p-Bromo nitrobenzene p-nitrobenzoyl chloride ammonium salt of alkylene dithiophosphoric acids CHORDIA,LEENA CHATURVEDI,ALOK p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
description |
p-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ('H and 31P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature. |
author |
CHORDIA,LEENA CHATURVEDI,ALOK |
author_facet |
CHORDIA,LEENA CHATURVEDI,ALOK |
author_sort |
CHORDIA,LEENA |
title |
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
title_short |
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
title_full |
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
title_fullStr |
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
title_full_unstemmed |
p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE |
title_sort |
p-nitrophenyl and p-nitrobenzoyl derivatives of 0,0' - alkylene dithiophosphate |
publisher |
Sociedad Chilena de Química |
publishDate |
2008 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002 |
work_keys_str_mv |
AT chordialeena pnitrophenylandpnitrobenzoylderivativesof00alkylenedithiophosphate AT chaturvedialok pnitrophenylandpnitrobenzoylderivativesof00alkylenedithiophosphate |
_version_ |
1718445393048502272 |