SYNTHESIS, STRUCTURE AND PROPERTIES OF [GD(C6N0(2)H5)3(H(2)0)2](2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex ]GD(C6N0(2)H5)3(H(2)0)2](2N)(NH(5)0(2))(NZNCL5)(2NZNCL4)(2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex...
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| Autores principales: | , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2008
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400007 |
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| Sumario: | A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex ]GD(C6N0(2)H5)3(H(2)0)2](2N)(NH(5)0(2))(NZNCL5)(2NZNCL4)(2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is characteristic of a novel one-dimensional polycationic chain-like structure and unprecedented ZnCl5³~species. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.35 eV. Photoluminescent investigation reveáis that the title complex displays a strong blue-light fluorescent emission band. |
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