SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE

SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE

A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex &#093GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex...

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Autores principales: XIE,YI-MING, WU,JI-HUAI
Lenguaje:English
Publicado: Sociedad Chilena de Química 2008
Materias:
gadolinium
lanthanide
photoluminescence
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400007
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spelling oai:scielo:S0717-970720080004000072009-05-22SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCEXIE,YI-MINGWU,JI-HUAI gadolinium lanthanide photoluminescence A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex &#093GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is characteristic of a novel one-dimensional polycationic chain-like structure and unprecedented ZnCl5³~species. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.35 eV. Photoluminescent investigation reveáis that the title complex displays a strong blue-light fluorescent emission band.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.53 n.4 20082008-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400007en10.4067/S0717-97072008000400007
institution Scielo Chile
collection Scielo Chile
language English
topic gadolinium
lanthanide
photoluminescence
spellingShingle gadolinium
lanthanide
photoluminescence
XIE,YI-MING
WU,JI-HUAI
SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
description A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex &#093GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is characteristic of a novel one-dimensional polycationic chain-like structure and unprecedented ZnCl5³~species. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.35 eV. Photoluminescent investigation reveáis that the title complex displays a strong blue-light fluorescent emission band.
author XIE,YI-MING
WU,JI-HUAI
author_facet XIE,YI-MING
WU,JI-HUAI
author_sort XIE,YI-MING
title SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
title_short SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
title_full SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
title_fullStr SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
title_full_unstemmed SYNTHESIS, STRUCTURE AND PROPERTIES OF &#091GD(C6N0(2)H5)3(H(2)0)2&#093(2N)•(NH(5)0(2))(NZNCL5)(2NZNCL4)•(2NH(2)0) WITH STRONG FLUORESCENCE
title_sort synthesis, structure and properties of &#091gd(c6n0(2)h5)3(h(2)0)2&#093(2n)•(nh(5)0(2))(nzncl5)(2nzncl4)•(2nh(2)0) with strong fluorescence
publisher Sociedad Chilena de Química
publishDate 2008
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400007
work_keys_str_mv AT xieyiming synthesisstructureandpropertiesof091gdc6n02h53h2020932n8226nh502nzncl52nzncl482262nh20withstrongfluorescence
AT wujihuai synthesisstructureandpropertiesof091gdc6n02h53h2020932n8226nh502nzncl52nzncl482262nh20withstrongfluorescence
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