PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharg...
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Sociedad Chilena de Química
2009
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oai:scielo:S0717-970720090002000102009-10-07PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIESWANG,LIAN-LIANGHUA MA,PEIWEN,XIAN-MINGZHANG,KUNDENG,XIAO-CHUAN Li-ion battery LiFePO /C Silver modification EIS Li-ion diffusion coefficient LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharge capacity and rate capacity. Discharge capacities are improved from 130.8 mAhg-1 of LiFeP0(4)/Cto 149.8mAhg-1 of LiFeP0(4)/C+Ag cathodes. EIS measurements show that Silver modification slightly decreases the charge transfer resistance of LiFePOyC, and lithium ion diffusion coefficient is enhanced from 2.89 x 10-14 to 8.17 x 10-13m²s-1.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.2 20092009-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200010en10.4067/S0717-97072009000200010 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Li-ion battery LiFePO /C Silver modification EIS Li-ion diffusion coefficient |
spellingShingle |
Li-ion battery LiFePO /C Silver modification EIS Li-ion diffusion coefficient WANG,LIAN-LIANG HUA MA,PEI WEN,XIAN-MING ZHANG,KUN DENG,XIAO-CHUAN PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
description |
LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharge capacity and rate capacity. Discharge capacities are improved from 130.8 mAhg-1 of LiFeP0(4)/Cto 149.8mAhg-1 of LiFeP0(4)/C+Ag cathodes. EIS measurements show that Silver modification slightly decreases the charge transfer resistance of LiFePOyC, and lithium ion diffusion coefficient is enhanced from 2.89 x 10-14 to 8.17 x 10-13m²s-1. |
author |
WANG,LIAN-LIANG HUA MA,PEI WEN,XIAN-MING ZHANG,KUN DENG,XIAO-CHUAN |
author_facet |
WANG,LIAN-LIANG HUA MA,PEI WEN,XIAN-MING ZHANG,KUN DENG,XIAO-CHUAN |
author_sort |
WANG,LIAN-LIANG |
title |
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
title_short |
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
title_full |
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
title_fullStr |
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
title_full_unstemmed |
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES |
title_sort |
preparation and silver modification of lifepo4/c for li-ion batteries |
publisher |
Sociedad Chilena de Química |
publishDate |
2009 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200010 |
work_keys_str_mv |
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1718445402855833600 |