PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES

LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharg...

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Autores principales: WANG,LIAN-LIANG, HUA MA,PEI, WEN,XIAN-MING, ZHANG,KUN, DENG,XIAO-CHUAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200010
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spelling oai:scielo:S0717-970720090002000102009-10-07PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIESWANG,LIAN-LIANGHUA MA,PEIWEN,XIAN-MINGZHANG,KUNDENG,XIAO-CHUAN Li-ion battery LiFePO /C Silver modification EIS Li-ion diffusion coefficient LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharge capacity and rate capacity. Discharge capacities are improved from 130.8 mAhg-1 of LiFeP0(4)/Cto 149.8mAhg-1 of LiFeP0(4)/C+Ag cathodes. EIS measurements show that Silver modification slightly decreases the charge transfer resistance of LiFePOyC, and lithium ion diffusion coefficient is enhanced from 2.89 x 10-14 to 8.17 x 10-13m²s-1.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.2 20092009-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200010en10.4067/S0717-97072009000200010
institution Scielo Chile
collection Scielo Chile
language English
topic Li-ion battery
LiFePO /C
Silver modification
EIS
Li-ion diffusion coefficient
spellingShingle Li-ion battery
LiFePO /C
Silver modification
EIS
Li-ion diffusion coefficient
WANG,LIAN-LIANG
HUA MA,PEI
WEN,XIAN-MING
ZHANG,KUN
DENG,XIAO-CHUAN
PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
description LiFeP0(4)/C and LiFeP0(4)/C+Ag samples were prepared by sol-gel method. Samples were characterized by XRD, SEM, EIS and electrochemical discharge and charge tests. Silver modification does not affect the olivine structure of LiFeP0(4) but enhances its electrochemical performance in terms of discharge capacity and rate capacity. Discharge capacities are improved from 130.8 mAhg-1 of LiFeP0(4)/Cto 149.8mAhg-1 of LiFeP0(4)/C+Ag cathodes. EIS measurements show that Silver modification slightly decreases the charge transfer resistance of LiFePOyC, and lithium ion diffusion coefficient is enhanced from 2.89 x 10-14 to 8.17 x 10-13m²s-1.
author WANG,LIAN-LIANG
HUA MA,PEI
WEN,XIAN-MING
ZHANG,KUN
DENG,XIAO-CHUAN
author_facet WANG,LIAN-LIANG
HUA MA,PEI
WEN,XIAN-MING
ZHANG,KUN
DENG,XIAO-CHUAN
author_sort WANG,LIAN-LIANG
title PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
title_short PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
title_full PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
title_fullStr PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
title_full_unstemmed PREPARATION AND SILVER MODIFICATION OF LIFEPO4/C FOR LI-ION BATTERIES
title_sort preparation and silver modification of lifepo4/c for li-ion batteries
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200010
work_keys_str_mv AT wanglianliang preparationandsilvermodificationoflifepo4cforliionbatteries
AT huamapei preparationandsilvermodificationoflifepo4cforliionbatteries
AT wenxianming preparationandsilvermodificationoflifepo4cforliionbatteries
AT zhangkun preparationandsilvermodificationoflifepo4cforliionbatteries
AT dengxiaochuan preparationandsilvermodificationoflifepo4cforliionbatteries
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