SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained...
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Sociedad Chilena de Química
2009
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oai:scielo:S0717-970720090002000152009-10-07SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXESGULER,ERSIN Copper(II) Ligands Nickel(II) Oximes v1c-dioximes In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained and the obtained products were named as: anilino-1-acetyl-1-cyclohexeneglyoxime (C14H17N3O2), benzylamino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2), p-toluidino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2) respectively. Their transition metal complexes have been synthesized. The form of the obtained Ni(II) and Cu(II) complexes were found as square-planer as it is known usually. 'H n.m.r, conductivity measurements, magnetic properties, i.r spectra and elemental analyses data of ligands and complexes are given. In addition to this, thermal characterizations of the ligands and their complexes have been investigated.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.2 20092009-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200015en10.4067/S0717-97072009000200015 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Copper(II) Ligands Nickel(II) Oximes v1c-dioximes |
| spellingShingle |
Copper(II) Ligands Nickel(II) Oximes v1c-dioximes GULER,ERSIN SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| description |
In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained and the obtained products were named as: anilino-1-acetyl-1-cyclohexeneglyoxime (C14H17N3O2), benzylamino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2), p-toluidino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2) respectively. Their transition metal complexes have been synthesized. The form of the obtained Ni(II) and Cu(II) complexes were found as square-planer as it is known usually. 'H n.m.r, conductivity measurements, magnetic properties, i.r spectra and elemental analyses data of ligands and complexes are given. In addition to this, thermal characterizations of the ligands and their complexes have been investigated. |
| author |
GULER,ERSIN |
| author_facet |
GULER,ERSIN |
| author_sort |
GULER,ERSIN |
| title |
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| title_short |
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| title_full |
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| title_fullStr |
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| title_full_unstemmed |
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES |
| title_sort |
synthesis of three new vic-dioximes and their nickel(ii) and copper(ii) complexes |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2009 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200015 |
| work_keys_str_mv |
AT gulerersin synthesisofthreenewvicdioximesandtheirnickeliiandcopperiicomplexes |
| _version_ |
1718445403734540288 |