SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES

SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES

In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained...

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Autor principal: GULER,ERSIN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
Materias:
Copper(II)
Ligands
Nickel(II)
Oximes
v1c-dioximes
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200015
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spelling oai:scielo:S0717-970720090002000152009-10-07SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXESGULER,ERSIN Copper(II) Ligands Nickel(II) Oximes v1c-dioximes In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained and the obtained products were named as: anilino-1-acetyl-1-cyclohexeneglyoxime (C14H17N3O2), benzylamino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2), p-toluidino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2) respectively. Their transition metal complexes have been synthesized. The form of the obtained Ni(II) and Cu(II) complexes were found as square-planer as it is known usually. 'H n.m.r, conductivity measurements, magnetic properties, i.r spectra and elemental analyses data of ligands and complexes are given. In addition to this, thermal characterizations of the ligands and their complexes have been investigated.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.2 20092009-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200015en10.4067/S0717-97072009000200015
institution Scielo Chile
collection Scielo Chile
language English
topic Copper(II)
Ligands
Nickel(II)
Oximes
v1c-dioximes
spellingShingle Copper(II)
Ligands
Nickel(II)
Oximes
v1c-dioximes
GULER,ERSIN
SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
description In this study, anti-1-acetyl-l-cyclohexenylchloroglyoxime (C8H U C1N2O2) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexeneglyoxime. As a result of the reaction of C8HnC1N2O2with aryl- or arylalkylamines in ethanol between -10 °C and -15 °C , unsymmetrical vic-dioximes were obtained and the obtained products were named as: anilino-1-acetyl-1-cyclohexeneglyoxime (C14H17N3O2), benzylamino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2), p-toluidino -1-acetyl-1-cyclohexeneglyoxime (C15H19N3O2) respectively. Their transition metal complexes have been synthesized. The form of the obtained Ni(II) and Cu(II) complexes were found as square-planer as it is known usually. 'H n.m.r, conductivity measurements, magnetic properties, i.r spectra and elemental analyses data of ligands and complexes are given. In addition to this, thermal characterizations of the ligands and their complexes have been investigated.
author GULER,ERSIN
author_facet GULER,ERSIN
author_sort GULER,ERSIN
title SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
title_short SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
title_full SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
title_fullStr SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
title_full_unstemmed SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES
title_sort synthesis of three new vic-dioximes and their nickel(ii) and copper(ii) complexes
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200015
work_keys_str_mv AT gulerersin synthesisofthreenewvicdioximesandtheirnickeliiandcopperiicomplexes
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