STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD

STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD

In this work, the ruggedness of several variables suspected influents on extraction of ethylated organotins (butyl-and phenyltins) by Solid Phase Microextraction in headspace mode (HS-SPME) was realized by using Gas Chromatography-Pulsed Flame Photometric detection (GC-PFPD). The influence of eight...

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Autores principales: BRAVO,MANUEL, LESPES,GÄETANE, QUIROZ,WALDO, DE GREGORI,IDA, PINOCHET,HUGO, POTIN- GAUTIER,MARTINE
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200017
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spelling oai:scielo:S0717-970720090002000172009-10-07STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPDBRAVO,MANUELLESPES,GÄETANEQUIROZ,WALDODE GREGORI,IDAPINOCHET,HUGOPOTIN- GAUTIER,MARTINEIn this work, the ruggedness of several variables suspected influents on extraction of ethylated organotins (butyl-and phenyltins) by Solid Phase Microextraction in headspace mode (HS-SPME) was realized by using Gas Chromatography-Pulsed Flame Photometric detection (GC-PFPD). The influence of eight factors on SPME procedure was analyzed using an 11-factor, 12-experiment Plackett-Burman design on the chromatographic area normalized to either Tripropyltin or Diheptyltin area. After the results, the extraction of OTC by HS-SPME could be considered as rather robust as the factor effects were generally not significant or small when both internal standards were used.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.2 20092009-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200017en10.4067/S0717-97072009000200017
institution Scielo Chile
collection Scielo Chile
language English
description In this work, the ruggedness of several variables suspected influents on extraction of ethylated organotins (butyl-and phenyltins) by Solid Phase Microextraction in headspace mode (HS-SPME) was realized by using Gas Chromatography-Pulsed Flame Photometric detection (GC-PFPD). The influence of eight factors on SPME procedure was analyzed using an 11-factor, 12-experiment Plackett-Burman design on the chromatographic area normalized to either Tripropyltin or Diheptyltin area. After the results, the extraction of OTC by HS-SPME could be considered as rather robust as the factor effects were generally not significant or small when both internal standards were used.
author BRAVO,MANUEL
LESPES,GÄETANE
QUIROZ,WALDO
DE GREGORI,IDA
PINOCHET,HUGO
POTIN- GAUTIER,MARTINE
spellingShingle BRAVO,MANUEL
LESPES,GÄETANE
QUIROZ,WALDO
DE GREGORI,IDA
PINOCHET,HUGO
POTIN- GAUTIER,MARTINE
STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
author_facet BRAVO,MANUEL
LESPES,GÄETANE
QUIROZ,WALDO
DE GREGORI,IDA
PINOCHET,HUGO
POTIN- GAUTIER,MARTINE
author_sort BRAVO,MANUEL
title STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
title_short STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
title_full STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
title_fullStr STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
title_full_unstemmed STUDY OF RUGGEDNESS HS-SPME PROCEDURE FOR ORGANOTIN ANALYSIS BY GC-PFPD
title_sort study of ruggedness hs-spme procedure for organotin analysis by gc-pfpd
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200017
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