2,4,6-TRIMETHYLPYRIDINIUM CHLOROCHROMATE (TMPCC) AS AN EFFICIENT AND NOVEL OXIDIZING AGENT FOR THE CHEMOSELECTIVE OXIDATION OF ALCOHOLS TO THE CORRESPONDING CARBONYL COMPOUNDS
A simple and efficient chemoselective oxidation of alcohols to the corresponding aldehydes and ketones using 2,4,6-trimethylpyridinium chlorochromate (TMPCC) in acetonitrile was described. A good range of primary and secondary benzylic alcohols was selectively oxidized under reflux conditions in goo...
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| Autores principales: | , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2009
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000200022 |
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| Sumario: | A simple and efficient chemoselective oxidation of alcohols to the corresponding aldehydes and ketones using 2,4,6-trimethylpyridinium chlorochromate (TMPCC) in acetonitrile was described. A good range of primary and secondary benzylic alcohols was selectively oxidized under reflux conditions in good to excellent yields. |
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