SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE

This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two...

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Autores principales: ARANEDA,J.F, SALINAS,S, MAC-LEOD-CAREY,D, MUÑOZ-CASTRO,A, ARRATIA-PEREZ,R, ADAMS,C, CHÁVEZ,I, MANRÍQUEZ,J.M
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
Materias:
DFT
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014
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spelling oai:scielo:S0717-970720090003000142010-03-17SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENEARANEDA,J.FSALINAS,SMAC-LEOD-CAREY,DMUÑOZ-CASTRO,AARRATIA-PEREZ,RADAMS,CCHÁVEZ,IMANRÍQUEZ,J.M s-indaceno zirconium dicarbonyl,zirconocene DFT This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.3 20092009-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014en10.4067/S0717-97072009000300014
institution Scielo Chile
collection Scielo Chile
language English
topic s-indaceno
zirconium dicarbonyl,zirconocene
DFT
spellingShingle s-indaceno
zirconium dicarbonyl,zirconocene
DFT
ARANEDA,J.F
SALINAS,S
MAC-LEOD-CAREY,D
MUÑOZ-CASTRO,A
ARRATIA-PEREZ,R
ADAMS,C
CHÁVEZ,I
MANRÍQUEZ,J.M
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
description This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.
author ARANEDA,J.F
SALINAS,S
MAC-LEOD-CAREY,D
MUÑOZ-CASTRO,A
ARRATIA-PEREZ,R
ADAMS,C
CHÁVEZ,I
MANRÍQUEZ,J.M
author_facet ARANEDA,J.F
SALINAS,S
MAC-LEOD-CAREY,D
MUÑOZ-CASTRO,A
ARRATIA-PEREZ,R
ADAMS,C
CHÁVEZ,I
MANRÍQUEZ,J.M
author_sort ARANEDA,J.F
title SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
title_short SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
title_full SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
title_fullStr SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
title_full_unstemmed SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
title_sort synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014
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