SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two...
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Lenguaje: | English |
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Sociedad Chilena de Química
2009
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Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014 |
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oai:scielo:S0717-970720090003000142010-03-17SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENEARANEDA,J.FSALINAS,SMAC-LEOD-CAREY,DMUÑOZ-CASTRO,AARRATIA-PEREZ,RADAMS,CCHÁVEZ,IMANRÍQUEZ,J.M s-indaceno zirconium dicarbonyl,zirconocene DFT This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.3 20092009-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014en10.4067/S0717-97072009000300014 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
s-indaceno zirconium dicarbonyl,zirconocene DFT |
spellingShingle |
s-indaceno zirconium dicarbonyl,zirconocene DFT ARANEDA,J.F SALINAS,S MAC-LEOD-CAREY,D MUÑOZ-CASTRO,A ARRATIA-PEREZ,R ADAMS,C CHÁVEZ,I MANRÍQUEZ,J.M SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
description |
This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems. |
author |
ARANEDA,J.F SALINAS,S MAC-LEOD-CAREY,D MUÑOZ-CASTRO,A ARRATIA-PEREZ,R ADAMS,C CHÁVEZ,I MANRÍQUEZ,J.M |
author_facet |
ARANEDA,J.F SALINAS,S MAC-LEOD-CAREY,D MUÑOZ-CASTRO,A ARRATIA-PEREZ,R ADAMS,C CHÁVEZ,I MANRÍQUEZ,J.M |
author_sort |
ARANEDA,J.F |
title |
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
title_short |
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
title_full |
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
title_fullStr |
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
title_full_unstemmed |
SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE |
title_sort |
synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene |
publisher |
Sociedad Chilena de Química |
publishDate |
2009 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014 |
work_keys_str_mv |
AT aranedajf synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT salinass synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT macleodcareyd synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT munozcastroa synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT arratiaperezr synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT adamsc synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT chavezi synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene AT manriquezjm synthesischaracterizationofanewcarbonylatedzirconiummetalloceneusingadichlorozirconocenederivedfrompartiallyalkylatedsindacene |
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1718445408276971520 |