BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II

The miscibility behavior in blends containing poly(4-vinyl pyridine) (P4VPy) and poly(2-vinyl pyridine) (P2VPy) as polymer components and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methylendiphenol (MDP) as low molecular weight compounds (LMWC), was studied by Differential Scann...

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Autores principales:	GATICA,NICOLÁS, ALVARADO,NANCY
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2009
Materias:	compounds blends poly(4-vinyl pyridine) poly(2-vinyl pyridine) 4,4'-thiodiphenol 4,4'-methylendiphenol hydrogen bond low molecular weight
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300024
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spelling	oai:scielo:S0717-970720090003000242010-03-17BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IIGATICA,NICOLÁSALVARADO,NANCY compounds blends poly(4-vinyl pyridine) poly(2-vinyl pyridine) 4,4'-thiodiphenol 4,4'-methylendiphenol hydrogen bond low molecular weight The miscibility behavior in blends containing poly(4-vinyl pyridine) (P4VPy) and poly(2-vinyl pyridine) (P2VPy) as polymer components and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methylendiphenol (MDP) as low molecular weight compounds (LMWC), was studied by Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectrophotometry (FTIR) as main analytical techniques. The glass transition of P4VPy and the melting of TDP and MDP, were found to be significantly affected when the compounds were blended. This result was attributed to the miscibility between thern, as a direct consequence of the specific interactions between the blend components. FTIR was used to investígate these interactions. The formation of intermolecular hydrogen bonds between the pyridine nitrogen atoms and the hydroxyl groups of TDP and MDP were discovered. When P2VPy was the macromolecular component, a difference was observed in the DSC behavior, which was attributed to a steric hindrance effect. Thermogravimetric and viscometry analysis were also used as additional techniques to complement the FTIR and DSC measurements performed.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.3 20092009-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300024en10.4067/S0717-97072009000300024
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	compounds blends poly(4-vinyl pyridine) poly(2-vinyl pyridine) 4,4'-thiodiphenol 4,4'-methylendiphenol hydrogen bond low molecular weight
spellingShingle	compounds blends poly(4-vinyl pyridine) poly(2-vinyl pyridine) 4,4'-thiodiphenol 4,4'-methylendiphenol hydrogen bond low molecular weight GATICA,NICOLÁS ALVARADO,NANCY BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
description	The miscibility behavior in blends containing poly(4-vinyl pyridine) (P4VPy) and poly(2-vinyl pyridine) (P2VPy) as polymer components and the dihydric phenols 4,4'-thiodiphenol (TDP) and 4,4'-methylendiphenol (MDP) as low molecular weight compounds (LMWC), was studied by Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectrophotometry (FTIR) as main analytical techniques. The glass transition of P4VPy and the melting of TDP and MDP, were found to be significantly affected when the compounds were blended. This result was attributed to the miscibility between thern, as a direct consequence of the specific interactions between the blend components. FTIR was used to investígate these interactions. The formation of intermolecular hydrogen bonds between the pyridine nitrogen atoms and the hydroxyl groups of TDP and MDP were discovered. When P2VPy was the macromolecular component, a difference was observed in the DSC behavior, which was attributed to a steric hindrance effect. Thermogravimetric and viscometry analysis were also used as additional techniques to complement the FTIR and DSC measurements performed.
author	GATICA,NICOLÁS ALVARADO,NANCY
author_facet	GATICA,NICOLÁS ALVARADO,NANCY
author_sort	GATICA,NICOLÁS
title	BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
title_short	BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
title_full	BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
title_fullStr	BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
title_full_unstemmed	BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II
title_sort	blends of poly (vinyl pyridine)s and two dihydric phenols: thermal and infrared spectroscopic studies. part ii
publisher	Sociedad Chilena de Química
publishDate	2009
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300024
work_keys_str_mv	AT gaticanicolas blendsofpolyvinylpyridinesandtwodihydricphenolsthermalandinfraredspectroscopicstudiespartii AT alvaradonancy blendsofpolyvinylpyridinesandtwodihydricphenolsthermalandinfraredspectroscopicstudiespartii
_version_	1718445410080522240

BLENDS OF POLY (VINYL PYRIDINE)S AND TWO DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART II

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