SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE)
A diacid monomer of benzobisoxazole 2, 6-di(p-phenylene-carboxylic) acid (BBODPA) was synthesized in a simple procedure, and characterized by means of FTIR, ¹H NMR and 13C NMR. The resulting BBODPA was polymerized with 3, 3'-diaminobenzidine tetrahydrochloride (DAB) to prepare poly (bibenzimida...
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Sociedad Chilena de Química
2009
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oai:scielo:S0717-970720090004000012010-04-15SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE)YANHUA,LUJIANMIN,CHENHAIXIA,CUIHUIDI,ZHOU Copolymer polybenzimidazole polybenzoxazole thermal stability A diacid monomer of benzobisoxazole 2, 6-di(p-phenylene-carboxylic) acid (BBODPA) was synthesized in a simple procedure, and characterized by means of FTIR, ¹H NMR and 13C NMR. The resulting BBODPA was polymerized with 3, 3'-diaminobenzidine tetrahydrochloride (DAB) to prepare poly (bibenzimidazole-p-phenyl-benzobisoxazole) (PBBIBBO) in polyphosphonc acid. The inherent viscosities values of PBBIBBO indicated that it was a kind of high molecular weight polymer. The structure of PBBIBBO was confirmed by ¹H NMR, 13C NMR and FTIR. Thermal properties and dissolubility of PBBIBBO were also investigated. These results showed that PBBIBBO exhibited good thermal stability.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400001en10.4067/S0717-97072009000400001 |
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Scielo Chile |
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Scielo Chile |
language |
English |
topic |
Copolymer polybenzimidazole polybenzoxazole thermal stability |
spellingShingle |
Copolymer polybenzimidazole polybenzoxazole thermal stability YANHUA,LU JIANMIN,CHEN HAIXIA,CUI HUIDI,ZHOU SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
description |
A diacid monomer of benzobisoxazole 2, 6-di(p-phenylene-carboxylic) acid (BBODPA) was synthesized in a simple procedure, and characterized by means of FTIR, ¹H NMR and 13C NMR. The resulting BBODPA was polymerized with 3, 3'-diaminobenzidine tetrahydrochloride (DAB) to prepare poly (bibenzimidazole-p-phenyl-benzobisoxazole) (PBBIBBO) in polyphosphonc acid. The inherent viscosities values of PBBIBBO indicated that it was a kind of high molecular weight polymer. The structure of PBBIBBO was confirmed by ¹H NMR, 13C NMR and FTIR. Thermal properties and dissolubility of PBBIBBO were also investigated. These results showed that PBBIBBO exhibited good thermal stability. |
author |
YANHUA,LU JIANMIN,CHEN HAIXIA,CUI HUIDI,ZHOU |
author_facet |
YANHUA,LU JIANMIN,CHEN HAIXIA,CUI HUIDI,ZHOU |
author_sort |
YANHUA,LU |
title |
SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
title_short |
SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
title_full |
SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
title_fullStr |
SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
title_full_unstemmed |
SYNTHESIS OF POLY (BIBENZIMIDAZOLE-P-PHENYL- BENZOBISOXAZOLE) |
title_sort |
synthesis of poly (bibenzimidazole-p-phenyl- benzobisoxazole) |
publisher |
Sociedad Chilena de Química |
publishDate |
2009 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400001 |
work_keys_str_mv |
AT yanhualu synthesisofpolybibenzimidazolepphenylbenzobisoxazole AT jianminchen synthesisofpolybibenzimidazolepphenylbenzobisoxazole AT haixiacui synthesisofpolybibenzimidazolepphenylbenzobisoxazole AT huidizhou synthesisofpolybibenzimidazolepphenylbenzobisoxazole |
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1718445410616344576 |