MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY

The oxidation of leucine, isoleucine and valine by bis(dihydrogen tellurate)argentate(III) ion was studied by stopped-flow technique. It was both first order with respect to Ag(III) complex and amino acids. A plausible mechanism was proposed form the kinetics study. And the rate equations derived fr...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	HUO,SHUYING, SONG,CHANGYING, SHAN,JINHUAN, SHEN,SHIGANG, SUN,HANWEN
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2009
Materias:	Bis(dihydrogen tellurate)argentate(III) amino acid Kinetics and mechanism Redox reactions
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400013
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072009000400013
record_format	dspace
spelling	oai:scielo:S0717-970720090004000132010-04-15MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDYHUO,SHUYINGSONG,CHANGYINGSHAN,JINHUANSHEN,SHIGANGSUN,HANWEN Bis(dihydrogen tellurate)argentate(III) amino acid Kinetics and mechanism Redox reactions The oxidation of leucine, isoleucine and valine by bis(dihydrogen tellurate)argentate(III) ion was studied by stopped-flow technique. It was both first order with respect to Ag(III) complex and amino acids. A plausible mechanism was proposed form the kinetics study. And the rate equations derived from mechanism can explain all experimental phenomena. The activation parameters along with the second order rate constants were calculated.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400013en10.4067/S0717-97072009000400013
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Bis(dihydrogen tellurate)argentate(III) amino acid Kinetics and mechanism Redox reactions
spellingShingle	Bis(dihydrogen tellurate)argentate(III) amino acid Kinetics and mechanism Redox reactions HUO,SHUYING SONG,CHANGYING SHAN,JINHUAN SHEN,SHIGANG SUN,HANWEN MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
description	The oxidation of leucine, isoleucine and valine by bis(dihydrogen tellurate)argentate(III) ion was studied by stopped-flow technique. It was both first order with respect to Ag(III) complex and amino acids. A plausible mechanism was proposed form the kinetics study. And the rate equations derived from mechanism can explain all experimental phenomena. The activation parameters along with the second order rate constants were calculated.
author	HUO,SHUYING SONG,CHANGYING SHAN,JINHUAN SHEN,SHIGANG SUN,HANWEN
author_facet	HUO,SHUYING SONG,CHANGYING SHAN,JINHUAN SHEN,SHIGANG SUN,HANWEN
author_sort	HUO,SHUYING
title	MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
title_short	MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
title_full	MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
title_fullStr	MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
title_full_unstemmed	MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY
title_sort	mechanistic investigation of oxidation of some amino acids by bis(dihydrogen tellurate)argentate(iii) ion in alkaline medium: a kinetic study
publisher	Sociedad Chilena de Química
publishDate	2009
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400013
work_keys_str_mv	AT huoshuying mechanisticinvestigationofoxidationofsomeaminoacidsbybisdihydrogentellurateargentateiiiioninalkalinemediumakineticstudy AT songchangying mechanisticinvestigationofoxidationofsomeaminoacidsbybisdihydrogentellurateargentateiiiioninalkalinemediumakineticstudy AT shanjinhuan mechanisticinvestigationofoxidationofsomeaminoacidsbybisdihydrogentellurateargentateiiiioninalkalinemediumakineticstudy AT shenshigang mechanisticinvestigationofoxidationofsomeaminoacidsbybisdihydrogentellurateargentateiiiioninalkalinemediumakineticstudy AT sunhanwen mechanisticinvestigationofoxidationofsomeaminoacidsbybisdihydrogentellurateargentateiiiioninalkalinemediumakineticstudy
_version_	1718445412847714304

MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM: A KINETIC STUDY

Ejemplares similares